• Scopus
  • Chinese Science Citation Database (CSCD)
  • A Guide to the Core Journal of China
  • CSTPCD
  • F5000 Frontrunner
  • RCCSE
Advanced search
WANG Xiao-qian, ZHANG Yang, YU Zhi-ming.. Preparation of an antibacterial N,O-carboxymethyl chitosan dye.[J]. Journal of Beijing Forestry University, 2016, 38(11): 104-110. DOI: 10.13332/j.1000-1522.20160112
Citation: WANG Xiao-qian, ZHANG Yang, YU Zhi-ming.. Preparation of an antibacterial N,O-carboxymethyl chitosan dye.[J]. Journal of Beijing Forestry University, 2016, 38(11): 104-110. DOI: 10.13332/j.1000-1522.20160112

Preparation of an antibacterial N,O-carboxymethyl chitosan dye.

More Information
  • Received Date: April 04, 2016
  • Published Date: November 29, 2016
  • Chitosan and reactive brilliant blue KN-R were used to prepare a novel N,O-carboxymethyl chitosan dye by a two-step reaction. FTIR, XRD and elemental analyzer were employed to explore the chemical groups and structure of the obtained new dye. Besides, the water solubility was tested using a UV-visible spectrophotometer. The color parameters and color fastness of N,O-carboxymethyl chitosan dye dyed veneers with impregnating in atmospheric pressure were measured using a color measuring instrument. The antibacterial property of N,O-carboxymethyl chitosan dye treated veneers was specific evaluated by colony counting method. The results showed that: numerous —OH and little —NH2 were replaced by —CH2COOH, and —SO-3 of the dye had a chemical reaction with protonated —NH+3 of N,O-carboxymethyl chitosan. The crystallinity of CTS was obviously decreased while the water solubility of N,O-carboxymethyl chitosan dye was notably improved. N,O-carboxymethyl chitosan dye obviously improved the dyeing effects and light fastness as well as water fastness were both enhanced. Additionally, the antibacterial properties of N,O-carboxymethyl chitosan dye were superior to reactive brilliant blue KN-R.
  • [1]
    [1]
    邓洪,廖齐,胡云楚.活性染料在木材染色中上染率的研究[J].染料与染色,2004,41(6):358-359.
    [2]
    吴晓凤,于志明,张扬.青杨生材纵向染色性能的研究[J].北京林业大学学报,2014,36(3):125-129.
    [2]
    DENG H, LIAO Q, HU Y C. Studies on the uptake of reactive dyes for dying wood [J]. Dyestuffs and Coloration, 2004,41(6):358-359.
    [3]
    WU X F, YU Z M, ZHANG Y. Dyeing property of xylem utilizing the axil direction of freshly-felled Populus cathayana [J]. Journal of Beijing Forestry University, 2014, 36(3):125-129.
    [3]
    宋磊,党奇峰,刘成圣,等.N,O-羧甲基壳聚糖树脂的制备及其对重金属吸附性能研究[J].功能材料,2013,44(21): 3081-3084.
    [4]
    SONG L, DANG Q F, LIU C S, et al. Preparation of N,O-carboxymethyl chitosan resin and its adsorption for heavy metal ions [J].Journal of Functional Materials, 2013, 44(21): 3081-3084.
    [4]
    陈丽娜,周光明,薛莲,等.O-羧甲基化壳聚糖修饰磁性Fe3O4纳米粒子及其生物应用[J].功能材料,2008,39(7): 1199-1201.
    [5]
    WANG J L, CHEN C. Chitosan-based biosorbents: modification and application for biosorption of heavy metals and radionuclides [J]. Bioresource Technology, 2014, 160(5): 129-141.
    [5]
    CHEN L N, ZHOU G M, XUE L, et al. Preparation and bio application of O- carboxymethyl chitosan modified Fe3O4 magnetic nanoparticies [J]. Journal of Functional Materials, 2008, 39(7): 1199-1201.
    [6]
    VAKILI M, RAFATULLAH M, SALAMATINIA B, et al. Application of chitosan and its derivatives as adsorbents for dye removal from water and wastewater: a review [J]. Carbohydrate Polymers, 2014, 113: 115-130.
    [6]
    DUAN X F, LI J, LIU Y X. Studies on improvement of wood surface dyeing effects by pretreatment with chitosan [J]. China Wood Industry, 1997, 11(3): 11-14.
    [7]
    MATI-BAOUCHE N, ELCHINGER P H, DE BAYNAST H, et al. Chitosan as an adhesive [J]. European Polymer Journal, 2014, 60: 198-213.
    [7]
    ZHANG Y, YU Z M, ZHANG Y, et al. Color fixation mechanism of CTS-Ag and its effect on the properties of dyed veneer [J]. Journal of Beijing Forestry University,2015, 37(6):107-111.
    [8]
    SONG X Y, SHEN Y R. Dyeing with the reactive dyes[M]. Beijing: China Textile Press, 2009:550-558.
    [8]
    BABUK M, RAVINDRA K B. Bioactive antimicrobial agents for finishing of textiles for health care products [J]. Journal of the Textile Institute, 2015, 106(7): 706-717.
    [9]
    MA Y, LIU P T, LIU Z. Preparation of carboxymethyl chitosan and its application in antimicrobial paper [J]. Journal of Functional Materials, 2010, 41(4): 648-651.
    [9]
    PARK S, KANG J H, LIM H A. Study on the change in physical and functional properties of paper by the addition of chitosan [J]. Journal of Korea TAPPI, 2010, 42(5): 37-46.
    [10]
    GAO M J, WANG Z Q, SUN L, et al. Preparation and antibacterial properties of chitosan modified silver nannoparticles [J]. Journal of Functional Materials, 2012, 43(8): 1038-1041.
    [10]
    段新芳,李坚,刘一星.壳聚糖前处理提高木材表面染色效果的研究[J].木材工业,1997,11(3):11-14.
    [11]
    TANG R L, YU Z M, ZHANG Y, et al. Mechanisms and properties of chitosan-assisted bamboo dyeing [J]. Bioresources, 2015, 10(2):3326-3336.
    [12]
    张颖,于志明,张扬,等.载银壳聚糖的固色机理及其处理染色薄木性能的研究[J].北京林业大学学报,2015,37(6):107-111.
    [13]
    Japanese Industrial Standards Committee. Antimicrobial products-test for antimicrobial activity and efficiency: JIS Z 2801—2010 [S]. Tokyo: Japanese Standards Association, 2010.
    [14]
    ZHENG X, ZHANG H, SHE Y, et al. Composite films of N,O-carboxymethyl chitosan and bamboo fiber [J]. Journal of Applied Polymer Science, 2014, 131(3):1082-1090.
    [15]
    宋心远,沈煜如.活性染料染色[M].北京:中国纺织出版社,2009:550-558.
    [16]
    马滢,刘鹏涛,刘忠.羧甲基壳聚糖的制备及其在抗菌纸中的应用[J].功能材料,2010,41(4): 648-651.
    [17]
    CHOI B K, KIM K Y. In vitro antimicrobial activity of a chitooligosaccharide mixture against actinobacillus actinomycetemcomitans and streptococcus mutans [J]. International Journal of Antimicrobial Agents, 2001, 18(6): 553-557.
    [18]
    SHI Z L, NEOH K G. Antibacterial and mechanical properties of bone cement impregnated with chitosan nanoparticles [J]. Biomaterials, 2006, 27(11): 2440-2449.
    [19]
    高敏杰,王志强,孙磊,等.壳聚糖修饰银纳米颗粒的制备及抗菌性能研究[J].功能材料,2012,43(8):1038-1041.
    [20]
    KONG M, CHEN X G, LIU C S, et al. Antibacterial mechanism of chitosan microshperes in a solid dispersing system against E.coli [J]. Colloids and Surfaces B: Biointerfaces, 2008, 65(2): 197-202.
  • Cited by

    Periodical cited type(4)

    1. 张艳艳,李欣怡,丁菲宇,张秀娟,高鹏,许青波,耿俊昭. 聚季铵盐抗菌棉织物的制备及抗菌耐洗性能. 河南工程学院学报(自然科学版). 2023(01): 1-5 .
    2. 吴芳玲,孙婷,王东凯. 壳聚糖在肺吸入制剂中的研究进展. 中国药剂学杂志(网络版). 2023(04): 221-231 .
    3. 张国梁,沈明哲,邢义虎,张栋,李新业. 人造集成薄木制备技术的研究进展分析. 林业机械与木工设备. 2022(08): 8-12+19 .
    4. 张艳艳,耿俊昭,吴军,李欣怡. 聚季铵盐抗菌棉织物的制备及其抗菌性能研究. 武汉纺织大学学报. 2022(06): 46-49 .

    Other cited types(1)

Catalog

    Article views (2104) PDF downloads (35) Cited by(5)

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return