• Scopus
  • Chinese Science Citation Database (CSCD)
  • A Guide to the Core Journal of China
  • CSTPCD
  • F5000 Frontrunner
  • RCCSE
Advanced search
Wu Yuhui, Zhang Shaodi, Ren Zizhong, Wang Mingzhi. Flame retardant properties of phytic acid and melamine treated wood[J]. Journal of Beijing Forestry University, 2020, 42(4): 155-161. DOI: 10.12171/j.1000-1522.20190406
Citation: Wu Yuhui, Zhang Shaodi, Ren Zizhong, Wang Mingzhi. Flame retardant properties of phytic acid and melamine treated wood[J]. Journal of Beijing Forestry University, 2020, 42(4): 155-161. DOI: 10.12171/j.1000-1522.20190406

Flame retardant properties of phytic acid and melamine treated wood

More Information
  • Received Date: October 22, 2019
  • Revised Date: November 12, 2019
  • Available Online: November 19, 2019
  • Published Date: April 26, 2020
  • ObjectiveWooden materials are easy to get ignited when furniture and buildings go up in flames. It can cause the fast fire spread and produce much toxic gases leading to the human death. In order to reduce the fire hazard of furniture and buildings, wood must be treated for fire retardancy. In this study, an intumescent flame retardant (IFR) system of phytic acid and melamine was prepared and used as a flame retardant of wood, the flame retardancy of the treated wood was then investigated. The purpose of this paper is to provide a new thought and enrich the IFR system.
    MethodTwo-step impregnation method was conducted to assemble the phytic acid-melamine flame retardant in the interior of Populus cathayana. The weight percent gain, bulking, pyrolysis and combustion behavior of the modified wood was assessed. The morphology of the residue of treated wood after combustion was analyzed in order to discuss the mechanism of phytic acid-melamine IFR system.
    ResultThe first peak of heat release rate and the total heat release of 15% phytic acid and 5% melamine treatment group (PM2) were reduced by 91.24% and 79.05% compared with that of control, respectively. The PM2 group showed stronger smoke suppression performance, and reduced the total smoke emission by 52.94% compared with the control group. The mean carbon monoxide yield of PM2 group was reduced by 51.29% compared with the P15% group. The amount of carbon residue of PM2 group was significantly increased, which was 69.58% higher than that of P15% group and 278.4% higher than that of the control group. The PM2 group had the optimum effect on promoting the residue and reducing the heat release.
    ConclusionThe phytic acid and melamine flame retardant system can be penetrated into the wood. The combined treatment of phytic acid and melamine can reduce the heat release rate, total heat release, total smoke release and CO yield of flame retardant treated wood. Phytic acid takes part in catalyzing the dehydration and carbonization of wood which leads to the lower temperature of degradation reaction and promotion of the formation of carbon residue of wood. The synergistic effect between phytic acid and melamine can enhance the formation of carbon residue of wood.
  • [1]
    Jiang G, Qiao J, Hong F. Application of phosphoric acid and phytic acid-adoped bacterial cellulose as novel proton-conducting membranes to PEMFC[J]. International Journal of Hydrogen Energy, 2012, 37(11): 9182−9192. doi: 10.1016/j.ijhydene.2012.02.195
    [2]
    周洋. 植酸掺杂改善聚苯胺和聚吡咯导电纸的阻燃性能研究[D]. 哈尔滨: 东北林业大学, 2014.

    Zhou Y. Improvement of flame retardancy of polyaniline and polypyrrole-deposited conductive paper through phytic acid doping[D]. Harbin: Northeast Forestry University, 2014.
    [3]
    Cheng X W, Guan J P, Tang R C, et al. Phytic acid as a bio-based phosphorus flame retardant for poly(lactic acid) nonwoven fabric[J]. Journal of Cleaner Production, 2016, 124: 114−119. doi: 10.1016/j.jclepro.2016.02.113
    [4]
    Cheng X W, Guan J P, Chen G Q, et al. Adsorption and flame retardant properties of bio-based phytic acid on wool fabric[J]. Polymers, 2016, 8(4): 122. doi: 10.3390/polym8040122
    [5]
    罗长宏. 无卤阻燃剂的制备研究[D]. 济南: 山东大学, 2007: 6−10.

    Luo C H. Preparation of halogen-free flame retardants[D]. Jinan: Shandong University, 2007: 6−10.
    [6]
    欧育湘, 赵毅, 韩廷解, 等. 环境友好型阻燃剂–三聚氰胺及其盐类[J]. 塑料, 2009, 38(2):35−37.

    Ou Y X, Zhao Y, Han T J, et al. Environmentally friendly flame retardant-melamine and its salts[J]. Plastics, 2009, 38(2): 35−37.
    [7]
    汪家铭. 我国三聚氰胺发展概况及市场前景[J]. 化工设计通讯, 2008, 34(2):15−22. doi: 10.3969/j.issn.1003-6490.2008.02.006

    Wang J M. General situation and prospect of melamin development in China[J]. Chemical Engineering Design Communications, 2008, 34(2): 15−22. doi: 10.3969/j.issn.1003-6490.2008.02.006
    [8]
    Zheng Z, Cui X, Wang H. Preparation of a novel phosphorus- and nitrogen-containing flame retardant and its synergistic effect in the intumescent flame-retarding polypropylene system[J]. Polymer Composites, 2015, 36(9): 1606−1619. doi: 10.1002/pc.23069
    [9]
    张少龙, 李斌, 张飞跃, 等. 金属改性 P-HZSM-5分子筛催化乙醇芳构化[J]. 物理化学学报, 2011, 27(6):1501−1508. doi: 10.3866/PKU.WHXB20110517

    Zhang S L, Li B, Zhang F Y, et al. Metal-modified P-HZSM-5 zeolite for catalytic aromatization of ethanol[J]. Acta Physico-Chimica Sinica, 2011, 27(6): 1501−1508. doi: 10.3866/PKU.WHXB20110517
    [10]
    高黎, 王正, 张双保, 等. 木纤维–回收塑料复合材料的燃烧特性研究[J]. 北京林业大学学报, 2007, 29(6):176−180. doi: 10.3321/j.issn:1000-1522.2007.06.030

    Gao L, Wang Z, Zhang S B, et al. Flammability properties of wood fiber-recycled plastic composite[J]. Journal of Beijing Forestry University, 2007, 29(6): 176−180. doi: 10.3321/j.issn:1000-1522.2007.06.030
    [11]
    王奉强, 王清文, 张志军, 等. CONE 法研究木材阻燃剂的阻燃性能[J]. 灭火剂与阻燃材料, 2010, 29(11):990−992.

    Wang F Q, Wang Q W, Zhang Z J, et al. The fire retardancy study of wood fire retardant by cone calorimeter[J]. Fire Science and Technology, 2010, 29(11): 990−992.
    [12]
    李坚, 王清文, 李淑君, 等. 用 CONE 法研究木材阻燃剂FRW 的阻燃性能[J]. 林业科学, 2002, 38(5):108−113. doi: 10.3321/j.issn:1001-7488.2002.05.018

    Li J, Wang Q W, Li S J, et al. A study on the fire retardancy of FRW fire retardant for wood by cone calorimeter[J]. Scientia Silvae Sinicae, 2002, 38(5): 108−113. doi: 10.3321/j.issn:1001-7488.2002.05.018
    [13]
    胡云楚. 硼酸锌和聚磷酸铵在木材阻燃剂中的成炭作用和抑烟作用[D]. 长沙: 中南林业科技大学, 2006.

    Hu Y C. Char Forming and smoke suppression function of zinc borate and ammonium polyphosphate on wood during combustion[D]. Changsha: Central South University of Forestry and Technology, 2006.
    [14]
    王真, 吴玉章, 马星霞. 木材及木质复合材料的燃烧发烟规律[J]. 南京林业大学学报(自然科学版), 2015, 39(4):121−126.

    Wang Z, Wu Y Z, Ma X X. Smoke regularity of wood and wood-based panels be burned[J]. Journal of Nanjing Forestry University (Natural Science Edition), 2015, 39(4): 121−126.
    [15]
    王明枝, 张宇, 曹金珍, 等. 硼酸–硼砂及甜菜碱处理定向刨花板的协效阻燃性能[J]. 北京林业大学学报, 2014, 36(1):114−120.

    Wang M Z, Zhang Y, Cao J Z, et al. Flame retardant performance of oriented strand board treated with boric acid-borax and polymeric betaine by cone calorimeter[J]. Journal of Beijing Forestry University, 2014, 36(1): 114−120.
  • Related Articles

    [1]Zhou Yunhong, Li Jianliang, Wang Lidong, Zou Jinlong, Liu Yanqing, Lu Jingxing, Zhao Wanning, Jia Zhongkui. Effects of thinning on litter decomposition of Larix principis-rupprechtii plantation[J]. Journal of Beijing Forestry University, 2021, 43(12): 29-37. DOI: 10.12171/j.1000-1522.20210114
    [2]Wang Lina, Wu Junwen, Dong Qiong, Shi Zhuogong, Hu Haocheng, Wu Danzi, Li Luping. Effects of tending and thinning on non-structural carbon and stoichiometric characteristics of Pinus yunnanensis[J]. Journal of Beijing Forestry University, 2021, 43(8): 70-82. DOI: 10.12171/j.1000-1522.20210115
    [3]Jia Weiwei, Luo Tianze, Li Fengri. Branch density model for Pinus koraiensis plantation based on thinning effects[J]. Journal of Beijing Forestry University, 2021, 43(2): 10-21. DOI: 10.12171/j.1000-1522.20200057
    [4]Chen Beibei, Jiang Jun, Lu Yuanchang, Liu Xianzhao, Jia Hongyan, Ming Angang, Zhang Xianqiang. Effects of thinning intensity on the growth of interplanting broadleaved trees under Pinus massoniana plantation[J]. Journal of Beijing Forestry University, 2021, 43(1): 58-65. DOI: 10.12171/j.1000-1522.20200086
    [5]Hu Xuefan, Zhang Huiru, Zhou Chaofan, Zhang Xiaohong. Effects of different thinning patterns on the spatial structure of Quercus mongolica secondary forests[J]. Journal of Beijing Forestry University, 2019, 41(5): 137-147. DOI: 10.13332/j.1000-1522.20190037
    [6]ZHANG Tian, ZHU Yu-jie, DONG Xi-bin. Effects of thinning on the habitat of natural mixed broadleaf-conifer secondary forest in Xiaoxing'an Mountains of northeastern China[J]. Journal of Beijing Forestry University, 2017, 39(10): 1-12. DOI: 10.13332/j.1000-1522.20170187
    [7]SUN Zhi-hu, WANG Xiu-qin, CHEN Xiang-wei.. Effects of thinning intensity on carbon storage of Larix olgensis plantation ecosystem.[J]. Journal of Beijing Forestry University, 2016, 38(12): 1-13. DOI: 10.13332/j.1000-1522.20160016
    [8]ZHANG Yi, WANG Chun-mei, XU Ke, HAN Jin-feng, YANG Xin-tong, LIN Jia-li. Short-term effect of increasing nitrogen deposition on greenhouse gas emissions in Zoige wetland, western China.[J]. Journal of Beijing Forestry University, 2016, 38(8): 54-63. DOI: 10.13332/j.1000-1522.20160048
    [9]WANG Xiong-bin, YU Xin-xiao, XU Cheng-li, , GU Jian-cai, ZHOU Bin, FAN Min-rui, JIA Guo-dong, LV xi-zhi. Effects of thinning on edge effect of Larix principisrupprechtii plantation.[J]. Journal of Beijing Forestry University, 2009, 31(5): 29-34.
    [10]LI Guo-lei, LIU Yong, XU Yang, GUO Bei, ZHANG Ke-dong, ZHAO Shuang-rong. Effects of thinning intensity on the development of undergrowth in Pinus tabulaeformis plantations[J]. Journal of Beijing Forestry University, 2007, 29(2): 70-75.
  • Cited by

    Periodical cited type(10)

    1. 罗光成,雷相东,史景宁,何潇,向玮,李玉堂. 基于潜在生产力的吉林省长白落叶松人工林立地质量评价. 北京林业大学学报. 2025(01): 1-10 . 本站查看
    2. 倪靖峰,吕世琪,王占印,周超凡,刘宪钊. 不同林龄华北落叶松优势木生长与空间结构的关联性. 陆地生态系统与保护学报. 2024(01): 1-10 .
    3. 徐罗,亢新刚,陈月明,刘旭. 依据单因子评价体系的天然云冷杉针阔混交林立地质量评价. 东北林业大学学报. 2024(12): 25-31 .
    4. 周甲敏,刘兆刚,董灵波. 基于蓄积潜在生产力的小兴安岭阔叶混交林立地质量评价. 北京林业大学学报. 2024(12): 21-29 . 本站查看
    5. 龚宇浩,孙益群,董晨,胡彦蓉,高威芳. 基于广义代数差分法和因子选择的杉木人工林立地质量评价. 浙江农林大学学报. 2023(06): 1282-1291 .
    6. 沈剑波,王应宽,雷相东,雷渊才,汪求来,叶金盛. 基于BP神经网络的广东省针阔混交异龄林立地质量评价. 北京林业大学学报. 2019(05): 38-47 . 本站查看
    7. 秦倩倩,王海燕,李翔,雷相东,解雅麟,郑永林,耿琦. 东北天然针阔混交林凋落物磷素空间异质性及其影响因素. 生态学报. 2019(12): 4519-4529 .
    8. 卢立华,冯益明,农友,李华,农良书,孙冬婧,黄德卫,明安刚. 基于林班尺度的森林立地类型划分与质量评价. 林业资源管理. 2018(02): 48-57 .
    9. 轩俊伟,朱静. 天山云杉立地指数地统计空间分析. 林业资源管理. 2017(03): 46-50 .
    10. 倪伟星. 闽北湿地松人工林立地质量精确评价. 武夷学院学报. 2017(12): 61-67 .

    Other cited types(9)

Catalog

    Article views (9069) PDF downloads (189) Cited by(19)

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return