Preparation and adsorption property of phytic acid modified wood flour

Ding Mengyi; Ren Qikai; Luo Jingying; Wang Mingzhi

doi:10.12171/j.1000-1522.20210273

Journal of Beijing Forestry University > 2022 > 44(2): 131-140. > DOI: 10.12171/j.1000-1522.20210273

Ding Mengyi, Ren Qikai, Luo Jingying, Wang Mingzhi. Preparation and adsorption property of phytic acid modified wood flour[J]. Journal of Beijing Forestry University, 2022, 44(2): 131-140. DOI: 10.12171/j.1000-1522.20210273

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Preparation and adsorption property of phytic acid modified wood flour

Key Laboratory of Wooden Material Science and Application of Ministry of Education, School of Material Science and Technology, Beijing Forestry University, Beijing 100083, China

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Received Date: July 21, 2021
Revised Date: November 14, 2021
Accepted Date: November 18, 2021
Available Online: November 25, 2021
Published Date: February 24, 2022

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Abstract

Abstract

Objective Exploring the performance of wood flour and modified wood flour from processing residues in the wood industry as an adsorbent for dye pollutants in wastewater provides a strategy for the high-value utilization of wood flour.
Method Wood flour-based adsorbent (PA-WF) was prepared by grafting wood flour with phytic acid (PA) as the green modifier. The surface morphology, element distribution, functional group, specific surface area, crystallinity, crystal structure and porosity of PA-WF were characterized by scanning electron microscope-EDS energy spectrum, infrared spectrum, X-ray diffractometer, and BET. The effects of mass ratio of phytic acid to wood flour, mass ratio of urea to wood flour, reaction temperature and reaction time on the grafting rate of wood flour were explored. Firstly, the effects of PA-WF grafting ratios on the adsorption capacity of methylene blue dye solution were analyzed, and the changing law of PA-WF adsorption capacity under different adsorption time and initial concentration of methylene blue dye were further explored.
Result With the mass ratio of phytic acid to wood flour was 2.5 to 5, the mass ratio of urea to wood flour was 3 to 50, the reaction temperature of 70 ℃, and the reaction time of 3 h, modified wood flour with a grafting rate of 11.31% can be prepared. PA was successfully grafted on the wood flour to introduce phosphate groups and increase the specific surface area, mean pore size and pore volume of wood flour, which was showed in SEM-EDS, ATR-FTIR, XRD and BET research. The adsorption test results showed that PA-WF had the best adsorption performance when the grafting rate was 8%, and the adsorption capacity was 22.53 mg/g, which was 114.57% higher than that of unmodified wood flour (10.50 mg/g). The adsorption process of the PA-WF conformed to the Langmuir adsorption isotherm equation and the quasi-second-order kinetic equation.
Conclusion We use proper conditions to prepare phytic acid grafted modified wood flour. It is speculated that the adsorption process of adsorbent belongs to ion-exchange monolayer chemical adsorption. Using the anionic phosphate group in phytic acid can greatly improve the adsorption performance of wood flour, which provides a new idea for the high-value utilization of wood flour.
- wood flour,
- adsorption,
- dye,
- graft modification,
- phytic acid

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References (34)

References

[1]	卢俊. 废弃木质材料制备高性能复合材料工艺研究[D]. 广州: 华南农业大学, 2016. Lu J. Research on preparation of high performance composite materials by waste wood materials[D]. Guangzhou: South China Agricultural University, 2016.
[2]	王静. 中国环境规制对木材加工业参与全球价值链的影响[D]. 北京: 北京林业大学, 2020. Wang J. The impact of Chinese environmental regulations on wood processing industry’s participation in global value chains[D]. Beijing: Beijing Forestry University, 2020.
[3]	Nan S, Wang T, Liu C. Preparation, characterization and photocatalytic study of wood-flour/β-cyclodextrin/TiO₂ hybrid composite[J]. Wood Science and Technology, 2016, 50(6): 1243−1260. doi: 10.1007/s00226-016-0826-0
[4]	Chen C J, Hu L B. Nanoscale ion regulation in wood‐based structures and their device applications[J/OL]. Advanced Materials, 2020 [2021−02−11]. http:// DOI: 10.1002/adma.202002890.
[5]	牛增元, 罗忻, 叶曦雯, 等. 高效液相色谱–质谱法测定电子电气产品塑料部件中偶氮染料释放的致癌芳香胺[J]. 色谱, 2014, 32(1): 34−39. doi: 10.3724/SP.J.1123.2013.08005 Niu Z Y, Luo X, Ye X W, et al. Determination of carcinogenic aromatic amines derived from azo colorants in plastic components of electrical and electronic products by high performance liquid chromatography-mass spectrometry[J]. Chinese Journal of Chromatography, 2014, 32(1): 34−39. doi: 10.3724/SP.J.1123.2013.08005
[6]	Ou J H, Yan J J, Xu T, et al. Fabrication of nickel-iron layered double hydroxides using nickel plating wastewater via electrocoagulation, and its use for efficient dye removal[J/OL]. Journal of Molecular Liquids, 2021 [2021−02−12]. http://DOI: 10.1016/j.molliq.2021.116246.
[7]	Gupta V K, Pathania D, Agarwal S, et al. Adsorptional photocatalytic degradation of methylene blue onto pectin-CuS nanocomposite under solar light[J]. Journal of Hazardous Materials, 2012, 243: 179−186. doi: 10.1016/j.jhazmat.2012.10.018
[8]	Deepak P, Sharma S, Singh P. Removal of methylene blue by adsorption onto activated carbon developed from Ficus carica bast[J]. Arabian Journal of Chemistry, 2017, 10: S1445−S1451. doi: 10.1016/j.arabjc.2013.04.021
[9]	Islam M R, Mostafa M G. Characterization of textile dyeing effluent and its treatment using polyaluminum chloride[J]. Applied Water Science, 2020, 10: 119. doi: 10.1007/s13201-020-01204-4
[10]	Donkadokula N Y, Kola A K, Iffat N, et al. A review on advanced physico-chemical and biological textile dye wastewater treatment techniques[J]. Reviews in Environmental Science and Bio/Technology, 2020, 19(3): 543−560. doi: 10.1007/s11157-020-09543-z
[11]	Ilgin P, Ozay H, Ozay O. Selective adsorption of cationic dyes from colored noxious effluent using a novel N-tert-butylmaleamic acid based hydrogels[J]. Reactive and Functional Polymers, 2019, 142: 189−198. doi: 10.1016/j.reactfunctpolym.2019.06.018
[12]	Yazidi A, Sellaoui L, Dotto G L, et al. Monolayer and multilayer adsorption of pharmaceuticals on activated carbon: application of advanced statistical physics models[J]. Journal of Molecular Liquids, 2019, 283: 276−286. doi: 10.1016/j.molliq.2019.03.101
[13]	Si H Y, Wang T, Xu Z W. Biosorption of methylene blue from aqueous solutions on β-cyclodextrin grafting wood flour copolymer: kinetic and equilibrium studies[J]. Wood Science and Technology, 2013, 47(6): 1177−1196. doi: 10.1007/s00226-013-0567-2
[14]	Tumlos R, Ting J L, Elias O, et al. Results of the study of chemical-, vacuum drying- and plasma-pretreatment of coconut (Cocos nucifera) lumber sawdust for the adsorption of methyl red in water solution[J]. Surface and Coatings Technology, 2011, 205: S425−S429. doi: 10.1016/j.surfcoat.2011.01.055
[15]	陈光浩. 杉木木屑对水中亚甲基蓝及刚果红的吸附性能研究[D]. 南宁: 广西大学, 2014. Chen G H. Adsorption characteristics of methylene blue and congo red on fir sawdust[D]. Nanning: Guangxi University, 2014.
[16]	蔡静. 改性木屑的制备及其对铜离子的吸附研究[D]. 北京: 北京化工大学, 2016. Cai J. The modification of sawdust and adsorption of copper ion from aqueous solution[D]. Beijing: Beijing University of Chemical Technology, 2016.
[17]	柏松, 冯亚娥, 骆斌, 等. 桤木木屑对废水中Hg²⁺的静态吸附[J]. 光谱实验室, 2011, 28(2): 973−976. doi: 10.3969/j.issn.1004-8138.2011.02.115 Bai S, Feng Y E, Luo B, et al. Static adsorption of Hg²⁺ from wast water by alder sawdust[J]. Chinese Journal of Spectroscopy Laboratory, 2011, 28(2): 973−976. doi: 10.3969/j.issn.1004-8138.2011.02.115
[18]	Tan Y, Wang K L, Yan Q, et al. Synthesis of amino-functionalized waste wood flour adsorbent for high-capacity Pb(II) adsorption[J]. ACS Omega, 2019, 4(6): 10475−10484. doi: 10.1021/acsomega.9b00920
[19]	Kalavathy M H, Karthikeyan T, Rajgopal S, et al. Kinetic and isotherm studies of Cu(II) adsorption onto H₃PO₄-activated rubber wood sawdust[J]. Journal of Colloid and Interface Science, 2005, 292(2): 354−362. doi: 10.1016/j.jcis.2005.05.087
[20]	Cheng X W, Guan JP, Chen G Q, et al. Adsorption and flame retardant properties of bio-based phytic acid on wool fabric[J]. Polymers, 2016, 8(4): 122. doi: 10.3390/polym8040122
[21]	Wang H, Wen X, Yang F, et al. Preparation of a novel two-dimensional carbon material and enhancing Cu(II) ions removal by phytic acid[J]. Environmental Earth Sciences, 2018, 77: 472. doi: 10.1007/s12665-018-7652-7
[22]	You H, Chen J C, Yang C, et al. Selective removal of cationic dye from aqueous solution by low-cost adsorbent using phytic acid modified wheat straw[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2016, 509: 91−98.
[23]	Cheng X W, Guan J P, Tang R C, et al. Phytic acid as a bio-based phosphorus flame retardant for poly(lactic acid) nonwoven fabric[J]. Journal of Cleaner Production, 2016, 124: 114−119. doi: 10.1016/j.jclepro.2016.02.113
[24]	Shao L, Li Y, Ma Z L, et al. Highly sensitive strain sensor based on a stretchable and conductive poly(vinyl alcohol)/phytic acid/NH₂-POSS hydrogel with a 3D microporous structure[J]. ACS Applied Materials & Interfaces, 2020, 12(23): 26496−26508.
[25]	黄国红, 敖日格勒, 冯玉, 等. AFM及其在植物纤维分析方面的应用[J]. 中华纸业, 2009, 30(15): 69−72. doi: 10.3969/j.issn.1007-9211.2009.15.016 Huang G H, Aorigele, Feng Y, et al. A review on AFM and its application to the analysis of plant fiber[J]. China Pulp & Paper Industry, 2009, 30(15): 69−72. doi: 10.3969/j.issn.1007-9211.2009.15.016
[26]	Schwanninger M, Rodrigues J C, Pereira H, et al. Effects of short-time vibratory ball milling on the shape of FT-IR spectra of wood and cellulose[J]. Vibrational Spectroscopy, 2004, 36(1): 23−40. doi: 10.1016/j.vibspec.2004.02.003
[27]	Olga D, Dmitry S. Investigation of lignins by FTIR spectroscopy[J]. Macromolecular Symposia, 2008, 265(1): 61−68. doi: 10.1002/masy.200850507
[28]	孙克时, 李志强, 张淑玲, 等. 水溶液共聚法合成耐盐性高吸水性树脂[J]. 化学与粘合, 2000(3): 105−107, 126. Sun K S, Li Z Q, Zhang S L, et al. Preparation of resins salt resisting and high water absorbing by water solution copolymerization[J]. Chemistry and Adhesion, 2000(3): 105−107, 126.
[29]	Nguyen T M, Chang S, Condon B, et al. Thermal decomposition reactions of cotton fabric treated with piperazine-phosphonates derivatives as a flame retardant[J]. Journal of Analytical and Applied Pyrolysis, 2014, 110: 122−129. doi: 10.1016/j.jaap.2014.08.006
[30]	Zhang L C, Yi D Q, Hao J W, et al. One-step treated wood by using natural source phytic acid and uracil for enhanced mechanical properties and flame retardancy[J]. Polymers for Advanced Technologies, 2021, 32(3): 1176−1186. doi: 10.1002/pat.5165
[31]	Cave I D. Theory of X-ray measurement of microfibril angle in wood[J]. Wood Science and Technology, 1997, 31(4): 225−234. doi: 10.1007/BF00702610
[32]	彭雄. 纤维素吸附材料的制备及其对六价铬和对氨基苯胂酸吸附性能研究[D]. 广州: 华南理工大学, 2020. Peng X. Preparation of cellulose adsorbent materials and study on their adsorption performance towards hexavalent chromium and p-arsanilic acid[D]. Guangzhou: South China University of Technology, 2020.
[33]	王洪杰, 兰依博, 李晓东. KMnO₄改性稻壳、稻杆水热炭吸附染料的研究[J]. 应用化工, 2019, 48(6): 1344−1350. Wang H J, Lan Y B, Li X D. Hydrothermal synthesis of KMnO₄ modified rice husk and rice straw and its adsorption properties[J]. Applied Chemical Industry, 2019, 48(6): 1344−1350.
[34]	徐金宝, 董文艺, 王宏杰, 等. KMnO₄改性活性炭对臭气中甲硫醇的吸附特性[J]. 环境工程学报, 2020, 14(6): 1570−1578. doi: 10.12030/j.cjee.201908130 Xu J B, Dong W Y, Wang H J, et al. Adsorption characteristics of methyl mercaptan in odor by KMnO₄ modified activated carbon[J]. Chinese Journal of Environmental Engineering, 2020, 14(6): 1570−1578. doi: 10.12030/j.cjee.201908130

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