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| Citation: |
Lei Yongrui, Lin Xixiang, Niu Wenxi, Li Zhuqi, Chen Hui, Li Jianzhang. Preparation and property of cottonseed meal adhesive reinforced by low-temperature defatted soybean meal[J]. Journal of Beijing Forestry University, 2024, 46(6): 137-144. DOI: 10.12171/j.1000-1522.20240082
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The influence mechanism of different soybean meal additions on the water-resistant bond strength and viscosity of modified cottonseed meal-based adhesive was clarified, which provided basis for industrial production and application of protein-based adhesive.
High-temperature dephenolized cottonseed meal, low-temperature defatted soybean meal and triglycidylamine were raw materials. The cottonseed meal adhesive modified by soybean meal was synthesized by controlling the addition amount of soybean meal and the ratio of raw materials. Then, poplar plywoods were prepared. The viscosity of the adhesive was measured by rotary rheometer. The structure and morphology of the adhesive were characterized by Fourier transform infrared spectrometer, X-ray crystal diffractometer and scanning electron microscope. Thermogravimetric analyzer and universal mechanical tensile tester were used to analyze the thermal stability and bond mechanical properties of the adhesive. Finally, the mechanism of bond enhancement of the modified adhesive was comprehensively analyzed.
With the increase of soybean meal content, the amount of lysine in the system increased, providing more active sites for cross-linking reaction, forming a mechanical interlocking effect of multiple crosslinking network structure, and improving the water-resistant bond performance and viscosity of the adhesive. When the addition of soybean meal was 10%, the dry strength and water-resistant bond strength of adhesive TCM/SM10 were 1.24 and 0.79 MPa, respectively. Compared with TCM, when the addition of soybean meal increased to 30%, the dry bond strength and water-resistant bond strength of the adhesive increased by 60.4% and 27.8%, reaching 1.54 and 0.92 MPa, respectively, and the viscosity of the adhesive increased to 20.689 Pa·s. The thermal stability and toughness were improved.
The use of low-temperature soybean meal as a partial substitute for cottonseed meal crosslinking modification to prepare cottonseed meal adhesive effectively improves the coating performance and water resistance of the adhesive, providing new ideas for the production of low-cost and high-performance protein based adhesives. It provides a new idea for producing modified cottonseed meal adhesive with low cost and high performance, and is helpful to promote the large-scale industrial application of protein-based adhesive.
| [1] |
苏慧东. 棉籽蛋白胶黏剂改性研究[D]. 泰安: 山东农业大学, 2021.
Su H D. Study on modification of cottonseed protein adhesive[D]. Taian: Shandong Agricultural University, 2021.
|
| [2] |
彭志翔. 脱脂棉籽粉木材胶黏剂的制备及其应用研究[D]. 福州: 福建农林大学, 2019.
Peng Z X. Preparation and application of defatted cottonseed meal wood adhesives[D]. Fuzhou: Fujian Agriculture and Forestry University, 2019.
|
| [3] |
Li J, Pradyawong S, Sun X S, et al. Improving adhesion performance of cottonseed protein by the synergy of phosphoric acid and water soluble calcium salts[J]. International Journal of Adhesion and Adhesives, 2021, 108: 102867. doi: 10.1016/j.ijadhadh.2021.102867
|
| [4] |
Lin Q, Zhang X, Cai W, et al. Improvement of the bonding performance of sucrose and ammonium dihydrogen phosphate adhesive by addition of dephenolized cottonseed protein[J]. Journal of Adhesion, 2023, 99(8): 1380−1401. doi: 10.1080/00218464.2022.2107905
|
| [5] |
Cheng H N, Kilgore K, Ford C, et al. Adhesive performance of cottonseed protein modified by catechol-containing compounds[J]. Journal of Adhesion Science and Technology, 2022, 36(16): 1781−1793. doi: 10.1080/01694243.2021.1984713
|
| [6] |
Connolly J M, Alferiev I, Clark-Gruel J N, et al. Triglycidylamine crosslinking of porcine aortic valve cusps or bovine pericardium results in improved biocompatibility, biomechanics, and calcification resistance[J]. American Journal of Pathology, 2005, 166(1): 1−13. doi: 10.1016/S0002-9440(10)62227-4
|
| [7] |
Kumar R, Choudhary V, Mishra S, et al. Adhesives and plastics based on soy protein products[J]. Industrial Crops and Products, 2002, 16(3): 155−172. doi: 10.1016/S0926-6690(02)00007-9
|
| [8] |
He Z, Cheng H N, Olanya O M, et al. Surface characterization of cottonseed meal products by SEM, SEM-EDS, XRD and XPS analysis[J]. Journal of Materials Science Research, 2017, 7(1): 28. doi: 10.5539/jmsr.v7n1p28
|
| [9] |
Jin S, Li K, Li J. Nature-inspired green procedure for improving performance of protein-based nanocomposites via introduction of nanofibrillated cellulose-stablized graphene/carbon nanotubes hybrid[J]. Polymers, 2018, 10(3): 270. doi: 10.3390/polym10030270
|
| [10] |
Zhang J, Zhang M, Zhang Y, et al. Improving bond performance and reducing cross-linker dosage for soy flour adhesives inspired by spider silk[J]. ACS Sustainable Chemistry & Engineering, 2020, 9(1): 168−179.
|
| [11] |
Cheng H N, Kilgore K, Ford C, et al. Cottonseed protein-based wood adhesive reinforced with nanocellulose[J]. Journal of Adhesion Science and Technology, 2019, 33(12): 1357−1368. doi: 10.1080/01694243.2019.1596650
|
| [12] |
Mi Y, Sun Z, Gao D, et al. Positive impact of carbohydrate on the crosslinking, performance, and potential applications of defatted soybean flour-based adhesive[J]. International Journal of Adhesion and Adhesives, 2021, 106: 102811. doi: 10.1016/j.ijadhadh.2021.102811
|
| [13] |
Bai Y, Zhao F, Shen J, et al. Improvement of water resistance of wheat flour-based adhesives by thermal-chemical treatment and chemical crosslinking[J]. Journal of Applied Polymer Science, 2021, 138(20): 50458. doi: 10.1002/app.50458
|
| [14] |
Wang Y, Deng Q, Song D, et al. Effects of fermented cottonseed meal on growth performance, serum biochemical parameters, immune functions, antioxidative abilities, and cecal microflora in broilers[J]. Food and Agricultural Immunology, 2017, 28(4): 725−738. doi: 10.1080/09540105.2017.1311308
|
| [15] |
Kang H, Wang Z, Wang Y, et al. Development of mainly plant protein-derived plywood bioadhesives via soy protein isolate fiber self-reinforced soybean meal composites[J]. Industrial Crops and Products, 2019, 133: 10−17. doi: 10.1016/j.indcrop.2019.03.022
|
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| |
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