Effects of P(MAA-co-BA) on the properties of PVC-wood flour composite.
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Graphical Abstract
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Abstract
In order to improve the compatibility between lipophilic PVC matrix and hydrophilic wood flour(WF), the copolymer P(MA-co-BA) of methyl acrylate and butyl acrylate was introduced into PVC-WF composite as compatibilizer. The effects of content of P(MAA-co-BA) and NaOH pretreatment to WF on the mechanical properties of the composite were studied and analyzed by means of FTIR, contact angle, DSC and SEM. The results showed that the interface compatibility of PVC and WF was benefited from P(MAA-co-BA), so the mechanical properties of composite were improved; but excessive P(MAA-co-BA) would reduce the mechanical properties.The tensile strength and impact strength of composite were enhanced by 70.9% and 64.7% respectively, when the content of P(MAA-co-BA) was 10% of wood flour. The mechanical properties of PVC-WF composite could be further enhanced by double treatment of NaOH and P(MAA-co-BA). FTIR spectra confirmed that the modified WF and P(MAA-co-BA) formed a chemical bond; and the contact angle analysis showed that the interfacial tension between modified WF and PVC declined. DSC confirmed that the compatibility of WF and PVC was improved after modification. SEM results also showed that the modification not only improved the dispersion of WF in PVC matrix, but improved the compatibility between WF and PVC.
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