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LIU Yan-hui, HOU Lian-xia, TIAN Jin-ling, REN Shi-xue.. Preparation and performance of hymexazol/lignin based amphoteric surfactant/bentonite slow-release formulation.[J]. Journal of Beijing Forestry University, 2015, 37(9): 101-110. DOI: 10.13332/j.1000-1522.20150142
Citation: LIU Yan-hui, HOU Lian-xia, TIAN Jin-ling, REN Shi-xue.. Preparation and performance of hymexazol/lignin based amphoteric surfactant/bentonite slow-release formulation.[J]. Journal of Beijing Forestry University, 2015, 37(9): 101-110. DOI: 10.13332/j.1000-1522.20150142
shu

Preparation and performance of hymexazol/lignin based amphoteric surfactant/bentonite slow-release formulation.

  • Key Laboratory of Bio-based Material Science and Technology, Ministry of Education, Northeast Forestry University, Harbin, Heilongjiang, 150040, P. R. China.

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  • Received Date: April 28, 2015
  • Published Date: September 29, 2015
    Graphical Abstract
    • Abstract
  • The use of slow-release formulation of pesticide is an effective strategy to reduce environmental pollution. In order to develop a slow-release formulation of low cost and with release regulation capability, and enhance the added value of lignin products, we used lignin-based amphoteric surfactant (dimethyl-butyl-sulfonated lignin ammonium chloride: DBSLAC) as modification agent to exchange the metal ions between the layer of sodium-based bentonite which was used as raw material, and prepared modified bentonite. Hymexazol was selected as the drug for release, and was loaded on modified bentonite. Hymexazol slow-release formulation was prepared by means of adsorption, its performance was studied, and its structure was characterized by FT-IR. The basal spacing of modified bentonite was analyzed with XRD. The results showed that with an increase of DBSLAC dosage, the adsorption capacity that modified bentonite adsorped hymexazol first increased and then decreased, and the optimum adsorption effect for acetaniprid was 1.2 CEC. Compared to the unmodified bentonite, the adsorption effect for hymexazol increased. The optimum adsorption conditions for hymexazol were L-1.2Bt dosage 0.02 g, adsorption time 8 h, mass concentration of acetaniprid 500 mg/L and pH 2. Under these conditions, the maximum adsorption capacity was 406 mg/g. The water soluble method indicated that potion proportion and temperature had certain effect on the accumulative release rate of L-1.2Bt.
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  • [1]
    LIU H T, WANG Z Y, ZHANG Y X, et al. Research on preparation of organophilic bentonite by hongquan bentonite from Jinchang area, Gansu province[J]. Non-Metallic Mines, 2011,34(2):46-49.
    [1]
    刘海涛,王卓亚,张有贤,等.甘肃金昌红泉膨润土制备有机膨润土的研究[J].非金属矿,2011,34(2):46-49.
    [2]
    WEN P,WU W J, GUO L M, et al. Properties of anion-cation organobentonite and decoloration of dyes onto it[J].China Surfactant Detergent Cosmetics, 2007, 37(6): 370-373.
    [2]
    温佩,武文洁,郭力梅,等.阴-阳离子有机膨润土的性能及对染料的脱色[J].日用化学工业,2007,37(6):370-373.
    [3]
    YAO M. Adsorption removal of persistent organic pollutants from dyeing wastewater by bentonite/surfactant in one-step process[D]. Hangzhong: Zhenjiang University, 2012.
    [3]
    姚敏.膨润土/表面活性剂一体化工艺吸附去除染化废水中的持久性有机污染物[D].杭州:浙江大学,2012.
    [4]
    WU G F, NIE J X, XIE W N, et al. Treatment of organic matters from micro-polluted water by combining modified bentonite with coagulant[J].Chinese Journal of Environmental Engineering, 2014, 8(10): 4302-4303.
    [4]
    吴光锋,聂锦旭,谢伟楠,等.改性膨润土联合混凝剂处理微污染水中有机物[J].环境工程学报,2014,8(10):4302-4303.
    [5]
    SHI B F, ZUO W Y, TONG H J. Adsorption of polycyclic aromatic hydrocarbons from queous solutions using modified bentonite[J].Chinese Journal of Environmental Engineering, 2015, 9(4): 1680-1685.
    [5]
    史兵方,左卫元,仝海娟.改性膨润土对水体中多环芳烃的吸附[J].环境工程学报,2015,9(4):1680-1685.
    [6]
    WANG T, ZHU R L, GE F, et al. Sorption of phenol and nitrobenzene in water by CTMAB/CPAM Organobentonites [J]. Environmental Science, 2010, 31(2): 385-389.
    [6]
    王通,朱润良,葛飞,等.CTMAB/CPAM复合改性膨润土吸附水中苯酚和硝基苯[J].环境科学,2010,31(2): 385-389.
    [7]
    黄子伦.膨润土基农药缓释剂的制备及其缓释性能研究[D].南宁:广西大学,2012.
    [7]
    HUANG Z L. Controlled release of pesticide from an organo-bentonite based formulation [D]. Nanning: Guangxi University, 2012.
    [8]
    REN J. Adsorption of carbofur onto organic bentonite in water [D].Qingdao: Ocean University of China, 2010.
    [8]
    任娟.有机膨润土对水中克百威的吸附研究[D].青岛:中国海洋大学,2010.
    [9]
    DONG Y, KONG Z J, LI P G, et al. Adsorption characteristics of organobentonite towards imidacloprid [J]. Journal of Guangxi University: Nat Sci Ed, 2013, 38(3): 569-575.
    [9]
    董燕,孔志杰,李平高,等.有机膨润土对吡虫啉的吸附[J].广西大学学报:自然科学版,2013,38(3): 569-575.
    [10]
    FANG R,CHENG X S. Study on the properties of ABS/lignin composites[J].Chemical Engineering Equipment, 2010(9) :6-9.
    [10]
    JIN Y Q, CHENG X S, ZHENG Z B. Preparation and characterization of phenol-formaldehyde adhesives modified with enzymatic hydrolysis lignin[J].Bioresour Technol,2010,101(6): 2046-2048.
    [11]
    ZHOU X Y, TANG L J, ZHENG F. Oxygen plasma-treated enzymatic hydrolysis lignin as a natural binder for manufacturing biocomposites[J]. International Journal of the Biology, Chemistry, Physics and Technology of Wood,2011,65(6):829-833.
    [11]
    ZHOU M S, MO X K, LOU H M, et al. Effects of different pretreated enzymatic hydrolysis lignins on reinforcement of acrylonitrile butadiene rubber[J].Journal of Chemical Engineering of Chinese Universities, 2014,28(4):831-835.
    [12]
    CAO Z N. Study on the properties of urea-formaldehyde resin modified with MMT lignin[D]. Hohhot:Inner Mongolia Agricultura University, 2010.
    [12]
    LI Y, HAN Y M, Qin T F, et al. Preparation of polyurethane foams based on liquefied corn stalk enzymatic hydrolysis lignin [J].Journal of Biobased Materials and Bioenergy,2012,6(1):51-58.
    [13]
    AI Q, SU L, ZHANG Q, et al. Preparation for porous titanium material with dimethyl-butyl-sulfonated lignin ammonium as a template[J].Journal of Beijing Forest University, 2013, 35(2): 102-107.
    [13]
    方润,程贤甦.ABS/木质素复合材料的性能研究[J].化学工程与装备,2010(9): 6-9.
    [14]
    周明松,莫贤科,楼宏铭,等.不同预处理酶解木质素对丁腈橡胶的补强性能研究[J].高校化学工程学报,2014,28(4):831-835.
    [14]
    HUANG Z L, CHEN L B, FU L H, et al. Controlled release of phoxim from organobentonite based ormulation[J]. Journal of Guangxi University, 2012, 37(5): 881-886.
    [15]
    曹振宁.蒙脱土、木质素改性尿醛树脂性能的研究[D].呼和浩特:内蒙古农业大学,2010.
    [15]
    ZENG Q R, ZHOU X H, YANG R B, et al. The adsorption of four pesticides in wastewater by cetyltrimethylammonium bromide(ctmab)modified bentonites[J]. Chinese Journal of Pesticide Science, 2000, 2(3): 80-84.
    [16]
    TIAN J L, REN S X, FANG G Z, et al.Synthesis and property of dimethyl-butyl-sulfonated lignin ammonium chloride[J].Chemistry and Industry of Forest Products, 2014, 34(4): 43-49.
    [16]
    DOHERTY W O S, MOUSAVIOUN P, FELLOWS C M. Value-adding to cellulosic ethanol: lignin polymers[J]. Industrial Crops and Products, 2011, 33(2): 259-276.
    [17]
    XIA X L, GU X P. Lignin modification with quaternary ammonium salt and its flocculation tests [J]. Guangzhou Chemical Industry, 2010, 38(4): 87-89.
    [17]
    艾青,苏玲,张琼,等.以二甲基-正丁基-磺化木质素基氯化铵为模板剂制备多孔钛材料[J].北京林业大学报,2013,35(2):102-107.
    [18]
    JING C J, XIAO B, REN J, et al. Adsorption of carbofuran on powdery and granular organobentonite[J]. Environmental Pollution Control, 2011 ,33(6): 65-70.
    [18]
    XU S,BOYD S A. Cationic surtactant adsorption by swelling and nonswelling layer silicates[J].Langmuir,1996,11:2508-2514
    [19]
    KWOLEK T, HODORAWICZ M, STADNICHA K. Adsorption isotherms of homologous alkyldimethylbenzylammonium bromides on sodium montmorillonite[J]. J Colloid Interface Sci,2003,264:14-19.
    [20]
    黄子伦,陈利标,付丽华,等.有机膨润土辛硫磷缓释剂的制备和释放研究[J].广西大学学报,2012,37(5):881-886.
    [21]
    曾清如,周细红,杨仁斌,等.CTMAB-膨润土对水溶液中4种农药的吸附特性[J].农药学学报,2000, 2(3): 80-84.
    [22]
    田金玲,任世学,方桂珍,等.二甲基-正丁基-磺化木质素基氯化铵的合成及性能研究[J].林产化学与工业,2014,34(4):43-49.
    [23]
    FAGERHOLMA H, JOHANSSOND L-S, ROSENHOL J B. A surface study on adsorption of lignosulpHonate on mixed Si3N4-Y2O3 powder dispersions[J].Journal of the European Ceramic Society,1994, 14(5): 403-409.
    [24]
    RATINAC K R, STAND O C, BRYANT P J. Lignosulfonate adsorption on and stabilization of lead zironate titanate in aqueous suspension[J].Colloid and Interface Science,2004,273:442-454.
    [25]
    夏旭林,古绪鹏. 季胺盐改性木质素及其絮凝性能试验 [J]. 广州化工,2010,38(4):87-89.
    [26]
    金春姬,肖波,任娟,等.粉末状和颗粒状有机膨润土对克百威的吸附[J].环境污染与防治,2011,33(6):65-70.
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