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    栓皮栎软木主要化学成分含量的地理差异

    Geographical differences in the content of main chemical components in cork of Quercus variabilis

    • 摘要:
        目的  通过大范围采样分析栓皮栎软木主要化学成分及其环境影响因素,以期为我国软木资源的定向选育与科学利用提供科学参考。
        方法  采集了全国12个地区栓皮栎软木进行软木脂、木质素等主要化学成分测定分析,通过LSD多重比较、主成分分析和聚类分析等方法,对不同样点软木化学成分进行比较。
        结果  发现栓皮栎软木主要化学成分的平均含量(本文中的化学成分含量指的是质量分数)为可萃取物(13.94 ± 0.54)%,软木脂(41.63 ± 1.44)%和木质素(23.03 ± 2.26)%。以软木脂与木质素含量进行聚类分析可将12个地理种源划分为3个类群,其中河北临城、江西永修、安徽金寨、江苏南京和河南内乡属于软木脂含量相对较高的类群;河南济源、陕西眉县和甘肃天水属于木质素含量较高的类群;陕西商洛、湖南城步、北京平谷和广西田林则属于中间类群。相关分析发现,二氯甲烷萃取物和总萃取物含量与纬度呈显著负相关关系,而软木脂含量随经度和土壤氮含量的增加呈现增加的趋势。年均温对化学成分含量的影响较小,但年均降水量与软木脂、二氯甲烷萃取物和总萃取物含量均呈现显著正相关关系。
        结论  整体上,我国栓皮栎软木化学成分含量存在一定的地理差异,且主要受纬度、年均降水量和土壤氮含量的影响。

       

      Abstract:
        Objective  This study aimed to analyze the main chemical constituents and environmental influencing factors of cork from Quercus variabilis through a wide range of samples in China, which would be helpful to provide scientific reference for the oriented selection and scientific utilization of cork resources.
        Method  Cork from Q. variabilis was collected from 12 regions in China for the determination of cork resin, lignin and other major chemical components, and the chemical components of cork from different locations were compared by LSD multiple comparison, principal component analysis and cluster analysis.
        Result  The average contents of main chemical constituents (the chemical composition content in this paper refers to the mass fraction) of the cork were: the total extractable matter was (13.94 ± 0.54)%, the suberin was (41.63 ± 1.44)% and the lignin was (23.03 ± 2.26)%. According to the content of suberin and lignin, the 12 provenances could be clustered into three groups, among which Lincheng (Hebei Province of northern China), Yongxiu (Jiangxi Province of eastern China), Jinzhai (Anhui Province of eastern China), Nanjing (Jiangsu Province of eastern China) and Neixiang (Henan Province of central China) had relatively high suberin content, while Jiyuan (Henan Province of central China), Meixian (Shaanxi Province of northwestern China) and Tianshui (Gansu Province of northwestern China) belong to the groups with high lignin content. The left provenances, Shangluo (Shaanxi Province of northwestern China), Chengbu (Hunan Province of southern China), Pinggu (Beijing of northern China) and Tianlin (Guangxi of southern China) belong to the middle group. The correlation analysis showed that the content of dichloromethane extract and total extractable matter was negatively correlated with latitude, while the suberin content increased with longitude and soil nitrogen content. The annual mean temperature had little effect on chemical composition content, but mean annual precipitation had significant positive correlation with the suberin, the dichloromethane extract and total extractable content.
        Conclusion  On the whole, there are certain geographical differences in the chemical composition content of cork from Quercus variabilis in China, and they are mainly affected by latitude, mean annual precipitation, and soil nitrogen content.

       

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