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    微波膨化木基金属复合材料的涂饰性能及耐光老化研究

    Painting properties and lightfastness of microwave puffed wood-based metal composites

    • 摘要:
      目的 微波膨化木基金属复合材料(PWMC)是一种密度适中、高导热、富有装饰性的新型金属木材料。为其未来在室内装饰、家居木制品等领域的高附加值应用提供技术支撑,开展了涂饰性能与耐光老化性的研究。
      方法 使用水性聚氨酯清漆涂饰PWMC,研究涂饰工艺对表面色度学参数和光泽度的影响,探讨砂纸目数与表面粗糙度间的关系。在紫外光老化条件下,研究光老化处理前后PWMC的色度学参数和光泽度变化,分析木材区域及表面聚氨酯涂层的光降解机理。
      结果 透明涂饰对PWMC发挥着保护与装饰的双重作用。三底两面透明涂饰处理后PWMC整体、木材和金属区域的总色差值分别为10.26、9.07和3.22,木材区域颜色变幅大于金属区域。涂饰后金属与木材两区域间的光泽度差异值由17.7降至2.3,表明涂饰处理能够有效降低光泽度差异。砂纸目数为240目时,PWMC各区域具有相近的粗糙度参数,差异值较小,表面平整且均一,此时漆膜附着力最佳(0级)。720 h光照下PWMC木材区域偏绿黄变化,木材与金属区域明度值增加;涂饰后木材与金属两区域的色度学参数变化幅度与失光率更低,证实了水性聚氨酯清漆对PWMC耐光性的提升作用。红外光谱与X射线光电子能谱显示PWMC木材区域与聚氨酯涂层中碳的氧化态升高,说明紫外光老化条件下发生了氧化降解。
      结论 本研究探明了微波膨化木基金属复合材料的涂饰性能与耐光性,为微波膨化木增值利用提供了理论和技术依据。

       

      Abstract:
      Objective Puffed wood-based metal composite (PWMC) is decorative metallic wood material with a high thermal conductivity and moderate density. To provide technical reference for its future high value-added applications in the fields of interior decoration and household wooden products, the research on painting properties and lightfastness of PWMC had been carried out in this paper.
      Method Waterborne polyurethane paints were coated on PWMC surface. We studied the effect of painting number on the colorimetric parameters and gloss. The relationship between sandpaper grit and film adhesion was investigated by comprehensively analyzing the surface roughness parameters. Meanwhile, the surface color changes and gloss loss rate were characterized after 720 h artificially accelerated UV ageing treatment. The photodegradation mechanism was also analyzed by comparing the surface chemical structures.
      Result Clear varnish finishes play a dual role of protection and decoration for PWMC. After the three-primers and two-topcoats painting treatment, the total color difference values of PWMC, wood area, and metal area were 10.26, 9.07 and 3.22, respectively. It indicated that the color variation of the wood area was larger than that of the metal area. The gloss value difference between wood and metal areas decreased from 17.7 to 2.3 after painting, representing that the painting treatment resulted in a more uniform surface gloss. The roughness parameters of PWMC wood and metal areas were similar when sandpaper grit was 240. It maintained a flat and homogeneous surface, thus PWMC had a best paint film adhesion (level 0). Under artificially accelerated UV ageing of 720 h, PWMC wood area changed to greenish-yellow, and the lightness of wood and metal areas increased. The colorimetric parameter changes and light loss rate of wood and metal areas were reduced after painting. It confirmed that the enhancement of waterborne polyurethane paints on the lightfastness of PWMC. Infrared spectroscopy and X-ray photoelectron spectroscopy showed an increase in the oxidation state of carbon atoms, indicating oxidative degradation happened in PWMC wood area and coating paints under light irradiation.
      Conclusion The painting properties and lightfastness are investigated, providing a theoretical and technical basis for the value-added utilization of PWMC.

       

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