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    竹纤维粒径与比例对石竹塑复合材料的性能影响

    Influence of bamboo fiber particle size and addition ratio on the properties of bamboo fiber/polypropylene/CaCO3 composite

    • 摘要:
      目的 阐明不同竹纤维粒径和原料配比对竹纤维/聚丙烯/碳酸钙复合材料物理力学性能的影响机理,为石竹塑复合材料的工业化生产与应用提供依据。
      方法 以碳酸钙、竹纤维和聚丙烯为原料,在控制竹纤维粒径(40目、80目和120目)与原料配比的基础上,制备竹纤维/聚丙烯/碳酸钙复合材料,考察其物理力学性能,并采用扫描电子显微镜、热重分析仪和熔融指数仪对复合材料的微观结构、热稳定性和流动性进行表征。最后,综合考虑生产成本与相关性能要求,为竹纤维/聚丙烯/碳酸钙复合材料的生产与应用提出建议。
      结果 随着碳酸钙添加量的增加,复合材料的拉伸强度、弯曲强度和弹性模量均逐渐下降,而密度则呈上升趋势。竹纤维粒径对复合材料物理力学性能的影响较为显著。当竹纤维粒径为80目,碳酸钙和竹纤维添加量分别为5%和45%时,复合材料的拉伸强度、弯曲强度和弹性模量最优,分别为36.09 MPa、62.6 MPa和4.30 GPa。碳酸钙添加量对复合材料冲击强度的影响不大。此外,随着碳酸钙添加量的增加,复合材料的热稳定性与熔体流动性均有所改善。当碳酸钙添加质量占比为20%时,复合材料的熔体流动速率为16.50 g/10 min,比未添加组提高了8.98%,加工性能得到改善。
      结论 选用80目竹纤维的复合材料具有较优的物理力学性能,在添加碳酸钙后,复合材料的原料成本可降低1.63% ~ 6.54%,且其相关指标仍远高于行业标准要求。

       

      Abstract:
      Objective The influence mechanism of different bamboo fiber particle sizes and raw material ratios on the physical and mechanical properties of bamboo fiber/polypropylene/calcium carbonate composites was expounded, which could provide reference for the industrial production and application of BFs/PP/CaCO3 composites.
      Method Taking calcium carbonate, bamboo fiber and polypropylene as the raw materials, BFs/PP/CaCO3 composites were prepared by controlling the particle size of bamboo fiber (40, 80 and 120 mesh) and the ratio of raw materials, and their physical and mechanical properties were investigated. The microstructure, thermal stability, and fluidity of the composites were characterized by scanning electron microscope, thermogravimetric analyzer, and melt index instrument, respectively. Finally, considering the production cost and related performance requirements, some suggestions were put forward for the production and application of BFs/PP/CaCO3 composites.
      Result With the increase of calcium carbonate content, the tensile strength, flexural strength, and elastic modulus of the composites decreased gradually, while the density increased. The particle size of bamboo fiber had a significant effect on the physical and mechanical properties of composites. When the particle size of bamboo fiber was 80 mesh, and the addition of calcium carbonate and bamboo fiber was 5% and 45%, respectively, the tensile strength, bending strength, and elastic modulus of the composites were the best, which were 36.09 MPa, 62.6 MPa and 4.30 GPa, respectively. The addition of calcium carbonate had little effect on the impact strength of composites. In addition, with the increase of calcium carbonate content, the thermal stability and melt fluidity of the composites also improved. When the proportion of calcium carbonate mass was 20%, the melt flow rate of the composites was 16.50 g/10 min, which was 8.98% higher than that of the group without calcium carbonate, thus the processability was improved.
      Conclusion The composite material with 80 mesh bamboo fiber exhibites excellent physical and mechanical properties. After adding calcium carbonate, the raw material cost of the composite material can be reduced by 1.63%−6.54%, and its related indexes were still far higher than the requirements of industry standards.

       

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