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    自褶皱UV固化聚氨酯丙烯酸酯木制品涂层的低光泽及抗指纹性能

    Low gloss and anti-fingerprint properties of self-wrinkling UV cured polyurethane acrylate wood coatings

    • 摘要:
      目的 褶皱结构广泛存在于自然界和我们的生活中,受这类天然结构的启发,人工制备的表面褶皱结构可以赋予材料低光泽度和抗指纹等一系列特殊性能。为了探究褶皱结构在木制品涂层上的应用,从褶皱形貌的变化来系统解释褶皱对涂层宏观性能的影响。
      方法 通过LED灯–准分子灯–UV汞灯分段固化系统,制备了一种可以在木制品表面自发形成褶皱的聚氨酯丙烯酸酯涂层,并进一步调节固化系统中的辐照能量,使涂层具有可控的光泽度和抗指纹性能。
      结果 当LED灯–准分子灯–UV汞灯辐照能量分别为200、15和300 mJ/cm2时,涂层在85°时的光泽度为5.2;此时涂层具有良好的抗指纹性能,表面的指纹可以在30 s内消失;涂层的机械性能也有一定提高,磨耗量达到最低为0.05 g/100 r,硬度由H提升为4H,附着力由2级提升为0级。同时对自褶皱涂层的耐久性也进行了研究,研究发现涂层在经过500次抗指纹测试后仍然能保持较低的光泽度。另外,由于褶皱表面的存在,涂层表面具有较好的耐黄变性能。
      结论 通过调节辐照能量可以改变自褶皱结构的波长和振幅,对聚氨酯丙烯酸酯涂层表面结构进行简单、高效和大规模的调控,褶皱表面使涂层具有低光泽和抗指纹的性能,同时提高了涂层的力学性能。

       

      Abstract:
      Objective The wrinkled structures are widely present in nature and our daily lives. Inspired by these natural structures, the artificial wrinkled structures on the material surfaces were prepared with a series of special properties such as low gloss and anti-fingerprint. To further explore the application of wrinkled structures on wood product coatings, the effects of wrinkles on the macroscopic properties were systematically explained from the changes of wavelength and amplitude on the wrinkled structures.
      Method A self-wrinkling polyurethane acrylate coating applied to the surface of wood products was prepared through the treatment of LED/excimer lamp/mercury lamp curing system. The irradiation energy in the curing system was adjusted to achieve controllable glossiness and fingerprint resistance of the coating.
      Result When the irradiation energy of LED lamp/excimer lamp/UV mercury lamp was 200, 15 and 300 mJ/cm2, respectively, the gloss value of the coating at 85° was 5.2. In addition, the coating samples had good anti-fingerprint performance, and the surface fingerprints can disappear within 30 seconds. Furthermore, the mechanical properties of the coating have also been improved with a minimum wear loss of 0.05 g/100 r, an increase in hardness from H to 4H, and an increase in adhesion from level 2 to level 0. Besides, due to the presence of self-wrinkling surfaces, the coating surfaces had good resistance to yellowing.
      Conclusion By adjusting the irradiation energy, the wavelength and amplitude of the self-wrinkling structures can be changed. The surface structures of polyurethane acrylate coatings can be easily and efficiently regulated on a large scale. The wrinkled surfaces endow the coating with low gloss and anti-fingerprint performance, while improving the mechanical properties of the coating.

       

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