Surface properties of Bruma rosewood polished using beewax modified by Nano-ZnO
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摘要: 为了提升传统烫蜡工艺处理后木材的表面性能,采用3种质量分数(0.5%、1.0%、2.0%)的纳米ZnO分别对烫蜡原料蜂蜡进行共混改性,并按照传统烫蜡工艺对缅甸花梨木试件进行表面改性蜂蜡烫蜡处理。采用扫描电子显微镜和能谱仪对处理材的微观形貌及纳米材料分散情况进行表征,通过分析处理材表面的耐紫外老化性、疏水性及抗菌性,探讨不同纳米ZnO含量对烫蜡后木材表面性能的影响。结果表明:经纳米ZnO改性蜂蜡烫蜡后的木材表面的颜色稳定性、疏水性和抗菌性均得到了明显改善。质量分数为1%的纳米ZnO改性蜂蜡处理材的表面性能最佳;96 h紫外老化后,其总色差较纯蜂蜡处理材降低了42%,接触角始终保持在102°以上;具备了显著的抗菌性,抑菌率可达65%。纳米 ZnO改性蜂蜡烫蜡后的木器颜色能够持久稳定,对于烫蜡木器使用范围的扩展具有重要意义。Abstract: In order to improve the surface properties of wood treated by traditional wax coating technology, the Bruma rosewood sample was treated by modified beewax, which was obtained by modifying nano ZnO with different mass ratios (0.5%, 1.0% and 2.0%). The morphology of the samples and the dispersion of nano ZnO were characterized by scanning electron microscopy (SEM ) and energy disperse spectroscopy (EDAX). The wood surface properties with different nano ZnO contents were investigated through ultraviolet aging resistance, hydrophobicity and antibacterial properties analysis. The results showed that the color stability, hydrophobicity and antibacterial properties were significantly improved after treated with the modified wax with nano ZnO. When the nano ZnO content was 1%, the wood surface properties were optimal. After 96 h ultraviolet aging, the total color difference (ΔE*) of the modified sample was reduced by 42% compared with the unmodified one. The contact angle of the modified sample kept always above 102°. The modified sample has remarkable antibacterial properties, and antibacterial rate reaches 65%. Wood color is stable after treated by nano ZnO modified wax, which has great significance for expanding the range of application of the wax polished wood.
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Keywords:
- nano ZnO /
- modified beewax /
- wax polish /
- Bruma rosewood /
- surface properties
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[1] 王秀林. 传统绝技:烫蜡[J].家具,2010(6):65-67. [1] WANG X L. Traditional consummate skill:tang-la[J]. Furniture,2010(6):65-67.
[2] YU Z Y. Function of the “Wax” in repairing of cultural relics[J]. Art Market,2012(5):66-69.
[2] 于子勇.“蜡”在文物保护修复中的功用[J].艺术市场,2012(5):66-69. [3] TONG D. The research on hot wax technology and decoration of furniture[D]. Harbin:Northeast Forestry University,2008.
[3] 佟达.家具烫蜡技术与装饰的研究[D].哈尔滨:东北林业大学,2008. [4] 牛晓霆,王逢瑚,佟达.影响仿明清硬木家具烫蜡质量的因素[J].林产工业,2011,38(2):46-49. [4] NIU X T,WANG F H,TONG D. Factors influencing the waxing quality of imitation Ming and Qing hardwood furniture[J]. Chinese Forestry Products Industry,2011,38(2):46-49.
[5] 牛晓霆,王逢瑚,赵俊学.明清家具的现代烫蜡技术[J].家具,2007(6):41-44. [5] NIU X T,WANG F H,ZHAO J X. The modern tangla technology of Ming And Qing furniture[J].Furniture,2007(6):41-44.
[6] 马建中,惠爱平,刘俊莉.纳米 ZnO 抗菌材料的研究进展[J].功能材料,2014,45(24):24001-24007. [6] MA J Z,HUI A P,LIU J L. Research progress on antibacterial materials of nano-ZnO[J]. Journal of Functional Materials,2014,45(24):24001-24007.
[7] SONG Y,YU Y,WANG G,et al. ZnO nano films self-assembly on the surface of bamboo wood and its anti-light discoloration properties[J]. Journal of Beijing Forestry University,2010,32(1):92-96.
[7] 宋烨,余雁,王戈,等. 竹材表面ZnO纳米薄膜的自组装及其抗光变色性能[J].北京林业大学学报,2010,32(1):92-96. [8] SUN J F,DAI Y J,WANG P C. Research status of nano-coatings[J]. Anhui Chemical Industry,2013,39(4):20-22.
[8] 孙巨福,戴宇均,汪鹏程. 纳米涂料的研究现状[J].安徽化工,2013,39(4):20-22. [9] FU Y C,YU H P,SUN Q F,et al. Testing of the superhydrophobicity of a zinc oxide nanorodarray coating on wood surface prepared by hydrothermal treatment [J]. Holzforschung,2012,66(12):739-744.
[9] GAO Y M,WU X K,LI S Y,et al. Property of PU coatings modified by nanometer zinc oxide [J]. Journal of Jiangsu University of Science and Technology(Natural Science Edition),2011,25(4):330-337.
[10] 高延敏,吴欣凯,李思莹,等. 纳米氧化锌改性及其对丙烯酸聚酯涂料性能影响[J]. 江苏科技大学学报(自然科学版),2011,25(4):330-337. [10] WANG L W,LI S C. Surface modification of Nano-ZnO and study on properties of WPU composite coating film[J]. Paint Coatings Industry,2012,42(3):5-8.
[11] TANG N N. Antibacterial modification of ZnO nano-particles and its application[D].Beijing: Beijing University of Chemical Technology,2014.
[11] YU Y,JIANG Z H,WANG G,et al. Growth of ZnO nano films on wood with improved photostability[J]. Holzforschung,2010,64(3):385-390.
[12] 王丽伟,李树材.纳米氧化锌表面改性及其复合水性聚氨酯涂膜性能的研究[J].涂料工业,2012,42(3):5-8. [12] WAN X L,ZHANG Q M,CHEN X H,et al. Preparation and properties of waterborne wood coatings modified with nano-ZnO[J]. Paint Coatings Industry,2014,44(12):25-28.
[13] 唐楠楠.纳米氧化锌颗粒抗菌修饰及在光固化涂料中的应用研究[D].北京:北京化工大学,2014. [13] DU L,LI R X,MIU G Y. Development of antibacterial water-borne wood coatings modified by nano materials[J].China Coatings,2007,22(6):35-48.
[14] 万祥龙,张启明,陈习惠,等. 纳米氧化锌改性水性木器涂料的制备与性能研究[J].涂料工业,2014,44(12):25-28. [14] WANG X D,TIE S L. Performance of nano-ZnO and its applications in coatings[J]. Electroplating Finishing,2005,24(3):27-30.
[15] SONG X H,WENG L,LI Q X. Research on the applications of nanometer SiO2 in coatings[J]. Refining and Chemicals,2004,15(2):12-13.
[15] 杜磊,李荣先,缪国元.纳米材料改性抗菌水性木器涂料的开发[J].中国涂料,2007,22(6):35-48. [16] 王小丹,铁绍龙.纳米氧化锌的性能及其在涂料中的应用[J].电镀与涂饰,2005,24(3):27-30. [16] HU J Q.Preparation and characterization of ZnO nano particle-reinforced polyurethane[D].Suzhou:Soochow University,2007:28-29.
[17] 宋晓华,翁凌,李群翔.纳米SiO2在涂料中的应用研究[J].炼油与化工,2004,15(2):12-13 [17] YANG F X,LIU Q L,BI L. Research on the application of Nano-Zinc Oxide[J]. Anhui Chemical Industry,2006(1):13-17.
[18] YANG Z. Preparation and properties of artificial bionic superhydrophobic functional surfaces[D]. Hefei: University of Science and Technology of China,2012:47.
[18] 胡剑青.纳米ZnO改性聚氨酯漆涂料的研究[D].苏州:苏州大学,2007:28-29. [19] 杨凤霞,刘其丽,毕磊.纳米氧化锌的应用综述[J].安徽化工,2006(1):13-17. [19] CHEN X. The study of preparation of nanometer ZnO improvement waterborne acrylic coating[D].Changchun:Changchun University of Science and Technology,2011:34.
[20] 杨周.仿生超疏水功能表面的制备及其性能研究[D].合肥:中国科学技术大学,2012:47. [20] XIANG R,DING D B,FAN L L. Antibacterial mechanism and safety of zinc oxide[J]. Chinese Journal of Tissue Engineering Research,2014,18(3):470-475.
[21] ZHANG X T,SATO O,FUJISHIMA A. Water ultrarepellency induced by nanocolumnar ZnO surface[J]. Langmuir,2004,20(14): 6065-6067.
[22] 陈鑫.纳米氧化锌改性水性丙烯酸涂料的制备与研究[D].长春:长春理工大学,2011:34. [23] 项容,丁栋博,范亮亮.氧化锌的抗菌机制及其安全性研究进展[J].中国组织工程研究,2014,18(3):470-475. -
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