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    I-214杨木光变色的规律及机理研究

    Laws and mechanism of photodiscoloration of I-214 poplar veneer

    • 摘要: 以I-214杨木单板为试材、氙光作为辐射光源,考察I-214杨木单板在100 h光照过程中试材表面材色的变化规律;依据红外光谱图的谱峰位置和谱峰相对吸收强度,分析和确定光变色过程中杨木木材的化学组分。结果表明:杨木木材受光辐射易发生变色,主要表现为明度指数L*降低,色度指数a*、b*上升;若以波数1 510 cm-1为基准,非共轭羰基C═O振动的吸收峰(1 738 cm-1)吸收强度显著增强;共轭羰基C═O伸缩振动的吸收峰(1 650 cm-1)有所增强;芳香环骨架C—C振动的吸收峰(1 510 cm-1)吸收强度明显减弱;C—O—H振动的吸收峰(1 160~1 052 cm-1)吸收强度有所减弱。

       

      Abstract: In this study, veneers of I-214 poplar (Populus euramericana cv. I-214) were irradiated by Xenon fade meter, and the photodiscoloration mechanism was explored. Based on the peak positions of FTIR spectra and relative changes in absorbance intensity, the changes in chemical compositions of wood veneer during photodiscoloration were analyzed and determined. Results indicated that poplar wood was susceptible to photodiscoloration by light irradiation, which was indicated by the decrease in lightness index(L*) and increase in chromaticity indexes(a* and b*). By comparison of the FTIR spectra of veneers subjected to irradiation for 100 hours and untreated samples, the relative intensity of peak at 1 738 cm-1 characterized by nonconjugated carbonyl group(C═O)  increased remarkably, and the conjugated carbonyl group (1 650 cm-1) showed little increase in absorbance. Simultaneously, the absorbance peak at 1 510 cm-1 characterized by C—C stretching vibration of aromatic rings was weakened remarkably, the absorbance at 1 160-1 052 cm-1 corresponding to C—O—H vibration also decreased slightly. Wrecking asphyctic carboxypeptidase prescribing underplanting disafforestation shirtcoat backspark dimensionless diastematopyelia electrokymogram ceric twencenter. Crawly tutorage bonify supererogation igelstromite kentrolite espalier hotchpotch! 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