Amide-modified casein water-based ink for printed decoration paper

Shi Fulin; Zhang Mingchang; Liu Ru; Long Ling; Dong Xiaoying; Li Xinyu

doi:10.12171/j.1000-1522.20240253

Journal of Beijing Forestry University > 2024 > 46(11): 148-156. > DOI: 10.12171/j.1000-1522.20240253

Shi Fulin, Zhang Mingchang, Liu Ru, Long Ling, Dong Xiaoying, Li Xinyu. Amide-modified casein water-based ink for printed decoration paper[J]. Journal of Beijing Forestry University, 2024, 46(11): 148-156. DOI: 10.12171/j.1000-1522.20240253

Citation:

PDF (8120 KB)

Amide-modified casein water-based ink for printed decoration paper

1.
Research Institute of Wood Industry, Chinese Academy of Forestry, Beijing 100091, China
2.
College of Forestry, Shandong Agricultural University, Tai’an 271018, Shandong, China
3.
Guangdong T & H New Material Co. Ltd., Foshan 528137, Guangdong, China

More Information

Received Date: August 11, 2024
Revised Date: November 03, 2024
Accepted Date: November 13, 2024
Available Online: November 15, 2024

Graphical Abstract

Abstract

Abstract

Objective
In order to solve the problem of low water resistance of traditional water-based inks for decoration paper and low impregnation resin amount of printed decoration paper, an amide compound modified casein water-based ink was prepared by chemical modification.
Method
Caprolactam (CPL), hydroxymethacrylamide (NMA) and diacetone acrylamide (DAAM) were used to co-modify casein to prepare modified casein emulsions, and the corresponding water-based inks and printed decoration papers were also prepared. By testing the properties of modified casein and the corresponding water-based inks and printed decoration papers, the changes in water resistance of water-based inks and impregnation resin amount of printed decoration papers, as well as the mechanism of the combined modification of casein by CPL, NMA and DAAM were analyzed.
Result
After adding the modifier to casein, a large number of amino groups were introduced into casein system, and a dense film could be formed after drying. The Zeta potential of modified casein emulsion was −45.0 mV, with the viscosity of 1 482.0 mPa·s, water contact angle of 14.2°, and soaking residual rate for 40 min of 80.5%. The water vapor transmission rate of modified casein film was 586.0 g/(m²·24 h), and its water permeability was significantly lower than that of casein film. Therefore, the water resistance of modified casein water-based ink printing decoration paper was significantly improved. There was no loss after soaking for 40 min, and the impregnation amount of printed decoration paper was higher than that of commercially purchased casein water-based ink. At 210 ℃, the color difference ΔE < 1, the color of printed decoration paper showed little change.
Conclusion
Compared with unmodified casein, the water and heat resistance of CPL, NMA and DAAM co-modified casein can be greatly improved, and the impregnation amount of printed decoration paper can meet the production requirements.
- paper,
- ink,
- chemical modification,
- amides,
- casein,
- printed decoration paper,
- impregnation resin amount,
- water resistance

FullText(HTML)

References (16)

References

[1]	杨杰, 刘永科, 陈庆. 浸渍胶树脂纸吸胶量对饰面中纤板表面性能的影响[J]. 木材工业, 2016, 30(6): 47−49. Yang J, Liu Y K, Chen Q. Effect of resin consumption of melamine-impregnated paper on surface performance of medium-density fiberboard[J]. Chinese Journal of Wood Science and Technology, 2016, 30(6): 47−49.
[2]	沈坤明. 水性油墨的透气性能和吸胶效率探讨[J]. 化工管理, 2017(2): 2. doi: 10.3969/j.issn.1008-4800.2017.02.045 Shen K M. Discussion on the air permeability and adhesive absorption efficiency of water-based inks[J]. Chemical Engineering Management, 2017(2): 2. doi: 10.3969/j.issn.1008-4800.2017.02.045
[3]	蒯舒洪. 水性装饰纸油墨的特点与使用[J]. 中国印刷, 2015(7): 90−92. doi: 10.3969/j.issn.1000-663X.2015.07.022 Kuai S H. Characteristics and use of water-based decorative paper inks[J]. China Print, 2015(7): 90−92. doi: 10.3969/j.issn.1000-663X.2015.07.022
[4]	Ma J, Xu Q, Gao D, et al. Blend composites of caprolactam-modified casein and waterborne polyurethane for film-forming binder: miscibility, morphology and properties[J]. Polymer Degradation and Stability, 2012, 97(8): 1545−1552. doi: 10.1016/j.polymdegradstab.2012.04.015
[5]	Koukiotis C, Sideridou I D. Synthesis and characterization of latexes based on copolymers BA\MMA\DAAM and BA\MMA\VEOVA-10\DAAM and the corresponding 1K crosslinkable binder using the adipic acid dihydrazide as crosslinking agent[J]. Progress in Organic Coatings, 2010, 69(4): 504−509.
[6]	王俊峰, 何玉凤, 王荣民, 等. 双丙酮丙烯酰胺的制备及应用研究进展[J]. 涂料工业, 2011, 41(2): 57−63. doi: 10.3969/j.issn.0253-4312.2011.02.015 Wang J F, He Y F, Wang R M, et al. Progress in preparation and applications of diacetone acrylamide[J]. Paint & Coatings Industry, 2011, 41(2): 57−63. doi: 10.3969/j.issn.0253-4312.2011.02.015
[7]	甘长凤. 核壳型酪素基水性油墨连接料的制备与性能研究 [D]. 西安: 陕西师范大学, 2014. Gan C F. Preparation and performance study of core-shell casein-based water-based ink binders [D]. Xi’an: Shaanxi Normal University, 2014.
[8]	雷亮. 塑料薄膜印刷用水性聚氨酯油墨连接料的制备及性能研究 [D]. 广州: 华南理工大学, 2015. Lei L. Preparation and performance study of waterborne polyurethane ink binder for plastic film printing [D]. Guangzhou: South China University of Technology, 2015.
[9]	曾冰蕙, 郝梦真, 刘桂蓉, 等. 酪蛋白糖基化改性的研究进展[J]. 食品工业科技, 2023, 44(6): 8. Ceng B H, Hao M Z, Liu G R, et al. Research progress on casein glycosylation modification[J]. Science and Technology of Food Industry, 2023, 44(6): 8.
[10]	刘燕. 酪蛋白胶束结构与功能特性的研究 [D]. 扬州: 扬州大学, 2007. Liu Y. Study on the structure and functional characteristics of casein micelle [D]. Yangzhou: Yangzhou University, 2007.
[11]	Carl H, John A, Carver. Quantitative multivalent binding model of the structure, size distribution and composition of the casein micelles of cow milk[J]. Science Direct, 2021, 126: 105292.
[12]	赵正涛, 李全阳, 赵红玲, 等. 酪蛋白在不同pH值下特性的研究[J]. 乳业科学与技术, 2009, 32(1): 4. Zhao Z T, Li Q Y, Zhao H L, et al. Study on the characteristics of casein at different pH values[J]. Dairy Science and Technology, 2009, 32(1): 4.
[13]	Bouzid H, Rabiller-Baudry M, Paugam L, et al. Impact of zeta potential and size of caseins as precursors of fouling deposit on limiting and critical fluxes in spiral ultrafiltration of modified skim milks[J]. Journal of Membrane Science, 2017, 314(1−2): 67−75.
[14]	Cui X S, Lei D, Yan X G, et al. Formation and characterization of the binary complex between zein and propylene glycol alginate at neutral pH[J]. Food Hydrocolloids, 2017, 64: 36−47.
[15]	Altan A, Aytac Z, Uyar T. Carvacrol loaded electrospun fibrous films from zein and poly (lactic acid) for active food packaging[J]. Food Hydrocolloids, 2018, 81: 58−49.
[16]	Mocanu A M, Moldoveanu C, Odochian L, et al. Study on the thermal behavior of casein under nitrogen and air atmosphere by means of the TG-FTIR technique[J]. Thermochimica Acta, 2012, 546: 120−126.

[1]	Liu Fangni, Yin Hao, Liu Zhiruo. Impact of greening around residential buildings on winter sunlight in Beijing[J]. Journal of Beijing Forestry University, 2024, 46(2): 114-122. DOI: 10.12171/j.1000-1522.20230056
[2]	Wang-Ren Zhongyuan, Zhang Shouhong, Zhang Sunxun, Yan Jing, Yang Hang, Wang Kai, Zhang Chengyu, Wei Liangyi. Effects of plant roots on the regulating function of green roof runoff[J]. Journal of Beijing Forestry University, 2023, 45(6): 108-116. DOI: 10.12171/j.1000-1522.20220274
[3]	Du Tiantian, Sun Xiangyang, Li Suyan, Zhou Wei, Zheng Yi, Fan Zhihui. Effects of landscaping waste mulching on soil fertility of urban green space[J]. Journal of Beijing Forestry University, 2021, 43(10): 110-117. DOI: 10.12171/j.1000-1522.20200402
[4]	Feng Xiaojie, Liu Guoliang, Zhang Wei, Sun Xiangyang, Li Suyan, Yan Subo. Effects of green waste compost on soil organic carbon fractions[J]. Journal of Beijing Forestry University, 2021, 43(7): 120-127. DOI: 10.12171/j.1000-1522.20210035
[5]	Zhang Deshun, Chen-Lu Qiyao, Xue Kaihua, Wang Zhen, Yao Chiyuan, Chen Yijia. Determination and analysis of the relationship between microclimate elements and greening structures in the city streets of Shanghai: taking Xuhui District and Yangpu District as examples[J]. Journal of Beijing Forestry University, 2021, 43(4): 124-131. DOI: 10.12171/j.1000-1522.20170359
[6]	Zhao Na, Li Shaoning, Xu Xiaotian, Wang Weina, Lu Shaowei. Water use efficiency and its influencing factors of typical greening tree species in Beijing region[J]. Journal of Beijing Forestry University, 2021, 43(3): 44-54. DOI: 10.12171/j.1000-1522.20200293
[7]	XIU Yu, WU Guo-dong, CHEN De-zhong, ZHAO Xiao-qing, TANG Wen-si, WANG Hua-fang. Propagation and afforestation techniques of tree peonies for greening and seed oil production[J]. Journal of Beijing Forestry University, 2017, 39(1): 112-118. DOI: 10.13332/j.1000-1522.20160045
[8]	LIU Li-na, XU Cheng-yang, DUAN Yong-hong, ZHOU Rui-zhi, DAI Xiang-yang. Root morphology of three greening conifer species in Beijing[J]. Journal of Beijing Forestry University, 2008, 30(1): 34-39.
[9]	SUI Jin-ling, ZHANG Xiang, HU De-fu, LI Kai, WANG Min-zhong, FU Rui-hai. Relationship between bird communities and environment factors at green belts in the urban area of Beijing[J]. Journal of Beijing Forestry University, 2007, 29(5): 121-126. DOI: 10.13332/j.1000-1522.2007.05.022
[10]	RAO Liang-yi, ZHU Jin-zhao, BI Hua-xing. Hydrological effects of forest litters and soil in the Simian Mountain of Chongqing City.[J]. Journal of Beijing Forestry University, 2005, 27(1): 33-37.

Cited By

Cited by

Periodical cited type(9)

1.	张薇，陆晓敏. 海盐乡土树种在城市园林中的应用调查与推广建议. 安徽农学通报. 2023(02): 79-82+96 .
2.	孙连群，何林洁，黄雪雯. 黔南州乡土植物资源在都匀市旅游景观中的运用. 黔南民族师范学院学报. 2023(03): 106-112+120 .
3.	饶显龙，何田恬，王冰彦，刘华红，李上善，丁洲，黎家宏，李珏. 浙江舟山群岛彩化植物资源调查及其园林应用评价. 北京林业大学学报. 2022(09): 127-136 . 本站查看
4.	简兴，鲍嵚，王雪娟. 屋顶绿化研究现状与展望. 世界林业研究. 2021(06): 14-19 .
5.	刘乐乐，朱亚灵，许宏刚，周德旗，汉梅兰. 兰州市城市绿地木本植物多样性研究. 草原与草坪. 2020(01): 56-62 .
6.	李荣喜，许雯，黄敏，张怡君，董斌. 广州市高架桥桥荫植物绿化现状及对策. 现代园艺. 2019(10): 148-150 .
7.	柳泽鑫，吴悦宏，肖泽鑫，陈翠蓉. 潮汕地区居住区乡土植物资源及其应用分析. 防护林科技. 2018(06): 40-42+45 .
8.	李峰，管志涛. 从建设海绵城市看濮阳市消落区植物景观配置. 濮阳职业技术学院学报. 2018(03): 110-112 .
9.	李成璋，黄永艺. 海绵城市建设理念下江门主城区园林乡土植物的利用研究. 绿色科技. 2018(21): 49-54 .

Other cited types(11)

Get Citation

PDF

XML

Article views (266) PDF downloads (54) Cited by(20)

Turn off MathJax

Article Contents

Abstract

References

Amide-modified casein water-based ink for printed decoration paper