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| Citation: |
Xu Huimin, Ru Kaixing, Ci Xiaolei, Wang Junya, Li Junying, Wang Junqing, Chen Sheng, Xu Feng. Fabrication of lignin containing nanocellulose and films from wheat straw pretreated by deep eutectic solvent[J]. Journal of Beijing Forestry University, 2024, 46(11): 141-147. DOI: 10.12171/j.1000-1522.20240260
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In order to efficiently utilize wheat straw raw materials, a new type of deep eutectic solvent (DES) was developed to achieve the preparation of lignin containing nanocellulose and the subsequent construction of functional materials.
Wheat straw was used as the raw material. Lignin containing nanocellulose was prepared by different DES pretreatments (benzyltrimethylammonium chloride-oxalic acid DES and benzyltriethylammonium chloride-oxalic acid DES) combined with high-pressure homogenization. Polyvinyl alcohol (PVA)/lignin containing nanocellulose composite films were prepared using the solution casting method. The study comparatively examined the microstructure, chemical groups, thermal stability, dispersibility lignin containing nanocellulose, as well as the optical properties, microstructure, and mechanical properties of composite films.
The residues of wheat straw pretreated by benzyltrimethylammonium chloride-oxalic acid DES showed smaller residue sizes and enhanced thermal stability. The obtained lignin containing nanocellulose exhibited stronger negative charge (−8.62 mV) and the composite films demonstrated higher haze (36.82%). In contrast, lignin containing nanocellulose prepared with benzyltriethylammonium chloride-oxalic acid DES maintained higher transparency of composite films (> 67%) and achieved a maximum film tensile strength of 57.16 MPa.
Benzyltrimethylammonium chloride-oxalic acid DES is more advantageous in enhancing the negative charge of lignin-containing nanocellulose and increasing haze of composite films. Benzyltriethylammonium chloride-oxalic acid DES is more effective in improving the transparency and mechanical strength of composite films, meeting the needs of different light management applications.
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