Structure and properties characterization of the flame retardant wood wallpaper.

LI Wei-yi; ZHANG Qiu-hui; ZHAO Guang-jie.

doi:10.13332/j.1000-1522.20150453

Journal of Beijing Forestry University > 2016 > 38(7): 91-97. > DOI: 10.13332/j.1000-1522.20150453

LI Wei-yi, ZHANG Qiu-hui, ZHAO Guang-jie.. Structure and properties characterization of the flame retardant wood wallpaper.[J]. Journal of Beijing Forestry University, 2016, 38(7): 91-97. DOI: 10.13332/j.1000-1522.20150453

Citation:

PDF (921 KB)

Structure and properties characterization of the flame retardant wood wallpaper.

MOE Key Laboratory of Wooden Material Science and Application, College of Materials Science and Technology, Beijing Forestry University, Beijing, 100083, P. R. China.

More Information

Received Date: December 01, 2015
Published Date: July 29, 2016

Graphical Abstract

Abstract

Abstract

We treated the decorative veneer and the nonwoven paper by ultrasonic impregnation with the composite flame retardant, and developed a new type of flame retardant wood wallpaper (FRWW). The flame retardant properties of FRWW were characterized by a cone calorimeter test (CCT) and compared with those of the PVC wallpaper. Field emission scanning electron microscopy (FE-SEM) and electron energy dispersive spectroscopy (EDS) were used to analyze the surface microstructure and the surface elements and content of FRWW. The functional groups of FRWW were characterized by Fourier infrared spectroscopy (FTIR). CIE1976 (L*a* b*) color space was used to characterize the color difference of the wood wallpaper before and after flame retardant treatment. Results showed that:1) Compared with the PVC wallpaper, the ignition time of FRWW was delayed 2 times; the heat release rate and the effective combustion heat were decreased by 8.88% and 30.79%, respectively. The total smoke release rate and the specific extinction area were reduced by 28.02% and 53.09% respectively. However, the total heat release, mass loss rate and CO release amount of FRWW and PVC had no marked difference. 2) The combustion growth rate index of FRWW decreased by 81.93%, and the fire performance index increased to 2.17 times higher than that of the PVC wallpaper, suggesting that the former has better fire safety level. 3) The flame retardant was distributed on the fiber pores of FRWW surface with irregular micron size distribution, and the main elements were C(31.15%), O(42.07%), N(19.77%), P(5.67%) and other trace elements. 4) The infrared absorption peak positions of the active functional groups (—NH and P—O—Ar) of FRWW were in 1 042 cm-1 and 1 015 cm-1, respectively. 5) The ΔE*ab of FRWW was only 1.734, showing that the flame retardant treatment has little effect on the decorative effect of the wood wallpaper.
- composite flame retardant,
- wood wallpaper,
- structure and properties,
- characterization

FullText(HTML)

References (48)

References

[1]	BAI G. Study on typical indoor BTEX sorption characteristics and impact factors of wallpaper[D]. Hangzhou: Zhejiang University, 2011.
[1]	MORISKE H J, EBERT G, LOTHAR K, et al. Concentrations and decay rates of ozone in indoor air in dependence on building and surface materials [J]. Toxicology Letters, 1998, 96-97:319-323.
[2]	CHEN X Y, XIANG S L, TAO T, et al. Research progress in fire-retardant treatment methods of woody materials[J]. China Forest Products Industry, 2012,39(5): 8-11.
[2]	YU K P, GRACE W M, HSIEH C P, et al. Evaluation of ozone generation and indoor organic compounds removal by air cleaners based on chamber tests [J]. Atmospheric Environment, 2011,45:35-43.
[3]	LI M Y, ZHU G Q, LI J Y, et al.The igniting and pyrolytic characteristics of several kings of common wallpaper[J]. Fire Science and Technology, 2014,33(5):487-490.
[3]	白鸽.墙纸对室内苯系物的吸附影响因素研究[D].杭州:浙江大学,2011.
[4]	CHEN X, YUAN L P, HU Y C, et al. Comparative study on the flame retarding and smoke suppressing properties of wood treated by manganese compounds[J]. Journal of Functional Materials, 2014,45(11):11076-11080.
[4]	USMAN S, RICHRD E L, RICHARD G, et al. Material and fire threat [J]. Fire Technology, 1997,33(3):260-275.
[5]	WANG Q W, ZHANG Z J, CHEN L, et al. Effects of oxygen concentration on the smoking property of fire-retardant treated wood [J]. Scientia Silvae Sinicae, 2006,42(2):95-100.
[5]	YOSHIHIKO A, SAKAE N, YUTA T, et al. Improvement on fire retardancy of wood flour/polypropylene composites using various fire retardants [J].Polymer Degradation and Stability, 2014,100:79-85.
[6]	CHU D M, MU J, ZHANG X T, et al. A comparative study on fire resistance of poplar treated with five kinds of nitrogen-phosphorus fire retardants by CONE calorimetry [J]. Journal of Southwest Forestry University, 2015, 35(3):83-89.
[6]	陈星艳,向士龙,陶涛,等.木质材料阻燃处理方法的应用研究进展[J].林产工业,2012,39(5):8-11.
[7]	LI J J, OU Y X. Flame retardant theory [M].Beijing: Science Press, 2013:81-84.
[7]	LI L M, ZHANG H P, XIE Q Y, et al. Experimental study on fire hazard of typical curtain materials in ISO 9705 fire test room [J].Fire and Materials,2012,36(2):85-96.
[8]	李梦媛,朱国庆,李俊毅,等.几种常见壁纸点燃与热解特性[J].消防科学与技术, 2014,33(5):487-490.
[8]	PENG Z H.New technology of polymer flame retardant[M]. Beijing: Chemical Industry Press, 2015:254-266.
[9]	QIAN L J. New flame retardant and application [M]. Beijing: Chemical Industry Press,2013:298-310.
[9]	SAKA S, TANNO E. Wood-inorganic composites prepared by the sol-gel process [J].Mokuzal Gakkaishi, 1996,42(1):81-86.
[10]	陈旬,袁利平,胡云楚,等. 两种锰化合物对木材阻燃抑烟作用的比较研究[J]. 功能材料, 2014,45(11):11076-11080.
[10]	ZHAO G J. Nano-dimensions in wood,nano-wood,wood and inorganic nano-composites [J]. Journal of Beijing Forestry University, 2002,24(5):6-9.
[11]	GU J W, ZHANG G C, DONG S L,et al. Study on preparation and fire-retardant mechanism analysis of intumescent flame retardant coatings[J].Surface and Coatings Technology,2007,201(18):7835-7841.
[11]	GB/T10739—2002 Paper, board and pulps: standard atmosphere for conditioning and testing [S]. Beijing: China Standard Press, 2002.
[12]	HUANG H H, TIAN M, LIU L, et al. Effects of silicon additive as synergists of Mg(OH)2 on the flammability of ethylene vinyl acetate copolymer[J].Journal of Applied Polymer Science,2006,99(6):3203-3209.
[12]	GB/T17359—2012 Microbeam analysis: quantitative analysis using energy dispersive spectrometry[S]. Beijing: China Standard Press, 2012.
[13]	GB/T7921—2008 Uniform color space and color difference formula [S]. Beijing: China Standard Press, 2008.
[13]	王清文,张志军,陈琳,等.氧浓度对阻燃木材发烟性能的影响[J].林业科学,2006,42 (2):95-100.
[14]	GB8624—2012 Classification for burning behavior of building materials and products[S]. Beijing: China Standard Press, 2012.
[14]	储德淼,母军,张晓藤,等.5种N-P阻燃剂阻燃抑烟性能的CONE分析[J].西南林业大学学报, 2015,35(3):83-89.
[15]	BLASI C D. The combustion process [M]∥TROITZCH J. Plastics flammability handbook. 3rd ed. Munich: Hanser Publishers, 2004:47-58.
[15]	LI J.Wood spectroscopy [M].Beijing: Science Press, 2003:109-110.
[16]	李建军,欧育湘.阻燃理论[M].北京:科学出版社, 2013:81-84.
[16]	NING Y C. Interpretation of organic spectra[M].Beijing: Science Press, 2010:106-115.
[17]	BOURBIGOT S, DUQUESNE S. Intumescence based fire retardants [M]∥WIKIE C A, MORGAN A B. Fire retardancy of polymeric material. 2nd ed. Boca Raton: CRC Press, 2009:129-162.
[18]	DUQUESNE S, BOURBIGOT S. Char formation and characterization [M]∥WILKIE C A, MORGAN A B. Fire retardancy of polymeric material. 2nd ed. Boca Raton: CRC Press, 2009:239-260.
[19]	彭治汉.聚合物阻燃新技术[M].北京:化学工业出版社,2015:254-266.
[20]	WANG D L, LIU Y, WANG D Y, et al. Novel intumescent flame-retardant system containing metal cheats for polyvinyl alcohol [J].Polymer Degradation and Stability,2007,92(8):1555-1564.
[21]	钱立军.新型阻燃剂与应用[M].北京:化学工业出版社,2013:298-310.
[22]	WANG Z Y, HAN E H, KE W. Fire-resistant effect of nanoclay on intumesent nanocomposite coatings [J]. Journal of Applied Polymer Science, 2007, 103(3):1681-1689.
[23]	赵广杰.木材中的纳米尺度、纳米木材及木材-无机纳米复合材料[J].北京林业大学学报,2002,24(5):6-9.
[24]	GB/T10739—2002纸、纸板和纸浆试样处理的试验的标准大气环境 [S].北京:中国标准出版社,2002.
[25]	ISO 5660-1:2002 Reaction-to-fire tests:heat release, smoke production and mass loss rate:Part 1: heat release rate (cone calorimeter method) [S]. Geneva:International standardization organization,2002.
[26]	GB/T17359—2012微束分析:能谱法定量分析 [S].北京:中国标准出版社,2012.
[27]	GB/T7921—2008均匀色空间及色差公式 [S].北京:中国标准出版社,2008.
[28]	BABRAUSKAS V, PEACOCK R D. Heat release rate: the single most important variable in fire hazard [J].Fire Safety Journal, 1992,18(3):255-272.
[29]	HANSEN A S. Prediction of heat release in the single burning item test [J].Fire and Material, 2002, 26(2):87-97.
[30]	GB8624—2012 建筑材料及制品燃烧性能分级[S].北京:中国标准出版社,2012.
[31]	李坚.木材波谱学[M].北京:科学出版社, 2003:109-110.
[32]	宁永成.有机波谱学谱图解析[M].北京:科学出版社, 2010:106-115.

[1]	Zhou Cheng, Liu Tong, Wang Qinggui, Han Shijie. Effects of long-term nitrogen addition on fine root morphological, anatomical structure and stoichiometry of broadleaved Korean pine forest[J]. Journal of Beijing Forestry University, 2022, 44(11): 31-40. DOI: 10.12171/j.1000-1522.20210212
[2]	Wu Chunbing, Wang Jingxue, Ji Xiaodong, Jiang Qian, He Jianjun, Liang Yushi. Spatial and temporal statistical characteristics of air density and its influence on basic wind pressure: a case study of Shandong Province, eastern China[J]. Journal of Beijing Forestry University, 2021, 43(5): 99-107. DOI: 10.12171/j.1000-1522.20210064
[3]	Zeng Aicong, Guo Xinbin, Zheng Wenxia, Wei Mao, Jin Quanfeng, Guo Futao. Temporal and spatial dynamic characteristics of forest fire in Zhejiang Province of eastern China based on MODIS satellite hot spot data[J]. Journal of Beijing Forestry University, 2020, 42(11): 39-46. DOI: 10.12171/j.1000-1522.20190483
[4]	Guan Zhuizhui, Zhang Yandong. Spatial and temporal distribution characteristics and discoloration law of Fraxinus mandshurica knot[J]. Journal of Beijing Forestry University, 2020, 42(8): 53-60. DOI: 10.12171/j.1000-1522.20200004
[5]	Zhang Jianjun, Chen Liqi, Li Jianguang, Sun Miao, Fan Yongming, Yu Xiaonan. Anatomical structure characteristics and growth ring analysis of underground rhizome of herbaceous peony[J]. Journal of Beijing Forestry University, 2020, 42(5): 124-131. DOI: 10.12171/j.1000-1522.20190096
[6]	Zhang Yichi, Guo Sujuan, Sun Chuanhao. Effects of growth retardants on anatomy and non-structural carbohydrates of chestnut leaves[J]. Journal of Beijing Forestry University, 2020, 42(1): 46-53. DOI: 10.12171/j.1000-1522.20180437
[7]	ZHONG Yue-ming, DONG Fang-yu, WANG Wen-juan, WANG Jian-ming, LI Jing-wen, WU Bo, JIA Xiao hong. Anatomical characteristics and adaptability plasticity of Populus euphratica in different habitats[J]. Journal of Beijing Forestry University, 2017, 39(10): 53-61. DOI: 10.13332/j.1000-1522.20170089
[8]	YAN Guo-yong, WANG Xiao-chun, XING Ya-juan, HAN Shi-jie, WANG Qing-gui. Response of root anatomy and tissue chemistry to nitrogen deposition in larch forest in the Great Xing’an Mountains of northeastern China[J]. Journal of Beijing Forestry University, 2016, 38(4): 36-43. DOI: 10.13332/j.1000-1522.20150433
[9]	WANG Ge, HAN Lin, ZHANG Yu, . Temporal variation and spatial distribution of NDVI in northeastern China.[J]. Journal of Beijing Forestry University, 2012, 34(6): 86-91.
[10]	ZHAO Yan-xia, LUO You-qing, ZONG Shi-xiang, WANG Rong1, LUO Hong-mei. Comparison in leaf anatomical structure and drought resistance of different sex and varieties of sea buckthorn[J]. Journal of Beijing Forestry University, 2012, 34(6): 34-41.

Cited By

Cited by

Periodical cited type(3)

1.	胡馨丹，李瑶，张小花，梁娟红，张腾国. 外源ATP对油菜幼苗耐寒性的影响. 植物研究. 2021(02): 302-311 .
2.	武永强，杨帆. 干扰Arf6抑制人前列腺癌细胞系DU145增殖、迁移及侵袭. 基础医学与临床. 2019(09): 1310-1315 .
3.	王浩然，吕雪芹，张越，满奕，荆艳萍. eATP在植物生长发育及逆境胁迫中的作用. 电子显微学报. 2017(01): 83-90 .

Other cited types(0)

Get Citation

PDF

XML

Article views (1982) PDF downloads (29) Cited by(3)

Turn off MathJax

Article Contents

Abstract

References

Structure and properties characterization of the flame retardant wood wallpaper.

Abstract

References

Related Articles

Cited by

Periodical cited type(3)

Other cited types(0)

Catalog

Structure and properties characterization of the flame retardant wood wallpaper.

Abstract

References

Related Articles

Cited by

Periodical cited type(3)

Other cited types(0)

Catalog

Export File

Citation

Format

Content