Preparation and structure characterization of biomass polyurethane rigid foam.

ZHOU Yu; HAN Wang; ZHAO Li-qing; AN Zhen.

doi:10.13332/j.1000-1522.20160068

Journal of Beijing Forestry University > 2016 > 38(10): 123-129. > DOI: 10.13332/j.1000-1522.20160068

ZHOU Yu, HAN Wang, ZHAO Li-qing, AN Zhen.. Preparation and structure characterization of biomass polyurethane rigid foam.[J]. Journal of Beijing Forestry University, 2016, 38(10): 123-129. DOI: 10.13332/j.1000-1522.20160068

Citation:

PDF (5402 KB)

Preparation and structure characterization of biomass polyurethane rigid foam.

College of Materials Science and Art Design, lnner Mongolia Agricultural University, Hohhot, 010018, P.R.China.

More Information

Received Date: March 03, 2016
Published Date: October 28, 2016

Graphical Abstract

Abstract

Abstract

In order to study the optimal preparation technological procedure for biomass polyurethane rigid foam, we take liquefaction products of Salix cheilophila and isocyanate as main ingredients, OMMT as nucleating agents, stannous octoate as a catalyst, water as foaming agent for foam experiment. The effects of isocyanate, stannous octoate, OMMT and water on the apparent density and compression strength of foam were studied. The structure performance of the foam was characterized and tested by XRD, TEM, SEM and TG analysis respectively. The results showed that the influence of factors on foams followed the sequence of catalyst, foaming agent, stannous octoate and foaming agent. Under optimal conditions, the foaming material had about 0.094 g/cm3 density and 0.416 MPa compression strength. Intercalated or exfoliated OMMT can be prepared by adding just the right amount, which can significantly improve the mechanical properties, thermal stability and flame retardance of materials.
- Salix cheilophila,
- liquefaction product,
- polyurethane foam,
- foaming process

FullText(HTML)

References (49)

References

[1]	谢涛, 谌凡更. 木材液化及其在高分子材料中的应用[J]. 纤维素科学与技术, 2004, 12(2): 47-53.
[1]	XIE T, SHEN F G. Wood liquefaction and application in polymer materials[J]. Journal of Cellulose Science and Technology, 2004, 12(2): 47-53.
[2]	LUO B, QIN T F, LI G Y. Liquefaction of wood and its utilizations[J]. China Wood Industry, 2004, 18(5): 5-7.
[2]	罗蓓, 秦特夫, 李改云. 木材的液化及其利用[J]. 木材工业, 2004, 18(5): 5-7.
[3]	周宇, 安珍. 沙柳材液化的工艺研究及产物分析[J]. 东北林业大学学报, 2015, 43(10): 109-113.
[3]	ZHOU Y, AN Z .Study on the liquefaction of salix and products analysis[J]. Journal of Northeast Forestry University, 2015, 43(10): 109-113.
[4]	ZHANG Q H, ZHAO G J. Research progress on mechanism of wood liquefaction reaction in phenol and polyhydric alcohols[J]. Chemistry and Industry of Forest Products,2014,34(4):138-143.
[4]	张求慧, 赵广杰. 木材的苯酚及多元醇液化反应机理研究进展[J]. 林产化学与工业,2014,34(4): 138-143.
[5]	HUANG J T,GAO G H. Aanlysis of NMR spectra on liquefied products from Salix psammophila and Caragana intermedia woods[J]. Chemistry and Industry of Forest Products, 2009, 29(4): 101-104.
[5]	黄金田, 高冠慧. 沙柳及柠条灌木材液化产物的核磁共振谱分析[J]. 林产化学与工业, 2009, 29(4):101-104.
[6]	ZHAO Y. The study on the technology and performance of the liquefaction product of salix[D]. Huhhot: Inner Mongolia Agricultural University, 2013.
[6]	赵岩. 沙柳液化物制备发泡材料的工艺与性能的研究[D]. 呼和浩特:内蒙古农业大学, 2013.
[7]	SHA F, MA D Q, LIU G, et al. Development and characterization of insulation decorative board with rigid polyurethane foam[J]. Building Energy Efficiency, 2010, 38(12):53-57.
[7]	沙丰, 马德强, 刘钢,等. 硬泡聚氨酷保温装饰板的开发与性能表征[J]. 建筑节能, 2010, 38(12): 53-57.
[8]	STOJANOVIAC＇U2 B V, JANEVSKI J N, MITKOVIAC＇U2 P B, et al. Thermally activated building systems in context of increasing building energy efficiency[J]. Thermal Science, 2014, 8(3): 1011-1018.
[8]	CHEN Y L, SHANG S S, YAN M, et al. Research status of thermal insulation wall materials[J]. Advanced Ceramics, 2015 (3): 20-24.
[9]	陈艳林, 尚珊珊, 严明,等. 保温隔热墙体材料的研究现状[J]. 现代技术陶瓷, 2015 (3): 20-24.
[9]	Standardization Administration of the People’s Republic of China. Cellular plastics and rubbers: determination of apparent density: GB/T 6343—2009[S]. Beijing: Standards Press of China, 2009.
[10]	Standardization Administration of the People’s Republic of China. Rigid cellular plastics: determination of compression properties: GB/T 8813—2008[S]. Beijing: Standards Press of China, 2008.
[10]	中国国家标准化管理委员会. 泡沫塑料及橡胶表观密度的测定:GB/T 6343—2009[S]. 北京: 中国标准出版社,2009.
[11]	中国国家标准化管理委员会. 硬质泡沫塑料压缩性能的测定:GB/T 8813—2008[S]. 北京:中国标准出版社,2008.
[11]	Standardization Administration of the People’s Republic of China. Plastics: determination of burning behavior by oxygen index: part 2: ambient-temperature test: GB/T2406.2—2009[S]. Beijing: Standards Press of China, 2009.
[12]	中国国家标准化管理委员会. 塑料:用氧指数法测定燃烧行为第2部分:室温试验:GB/T2406.2—2009[S]. 北京:中国标准出版社,2009.
[12]	LIU L Q, SUN F W, LIU Y, et al. Overview of bamboo liquefaction research and its applications[J]. China Wood Industry, 2012, 26(1): 15-19.
[13]	刘乐群, 孙丰文, 刘杨,等.竹材液化制备墙体新材料的研究进展[J]. 木材工业, 2012, 26(1): 15-19.
[13]	LIU Y H, GAO L L, LUO A X, et al. Polyurethane foams made from combined liquefaction mixtures of bamboo residues and starch[J]. Acta Polymerica Sinica, 2008(6): 544-549.
[14]	MIAO Y W. Preparation and properties of sandwich foam composite materials reinforced by SiC nanoparticles[D]. Huhhot: Inner Mongolia Agricultural University, 2014.
[14]	刘玉环, 高龙兰, 罗爱香,等. 毛竹屑与玉米淀粉共液化产物制备聚氨酯泡沫研究[J]. 高分子学报, 2008(6): 544-549.
[15]	WANG T P, MAO Z H. Effects of catalysts on mechanical properties of polyuerthane foams based on corn stalk[J]. Renewable Energy Resources, 2009, 27(6): 50-53,57.
[15]	苗雅文. SiC纳米粒子强化“三明治”发泡复合材料制备及其性能研究[D]. 呼和浩特:内蒙古农业大学,2014.
[16]	CAO X W, HE D, WU W, et al. Study on the effect of CaCO3 on open-cell foaming performance of polypropylene [J]. China Plastics Industry, 2011, 39(9): 57-60.
[16]	王体朋, 毛志怀. 催化剂对玉米秸秆基聚氨酯泡沫机械性能影响的研究[J]. 可再生能源, 2009, 27(6): 50-53,57.
[17]	HAN J Z, XIA Y, CAI Y F. Research progress of polymer/montmorillonite nanocomposites[J]. Plastics Manufacture, 2006, 34(10): 66-70.
[17]	曹贤武,何丁, 伍巍,等. 成核剂CaCO3对聚丙烯开孔发泡性能影响的研究[J]. 塑料工业, 2011, 39(9): 57-60.
[18]	韩建竹, 夏英, 蔡月芬. 聚合物/蒙脱土纳米复合材料的研究进展[J]. 塑料制造, 2006, 34(10): 66-70.
[18]	WANG G Y, CUI Y, LIN Y, et al. Effect of nucleate agent on mechanical properties of soft poly(vinyl chloride) extrusion foamed material[J]. Plastics, 2005, 34(3): 32-34.
[19]	XIAO F, YE J D, WANG Y J. Application of ultrasonic technique in the processing and synthesis of inorganic materials[J]. Journal of the Chinese Ceramic Society, 2002, 30(5): 615-619.
[19]	王国英, 崔毅, 林园,等. 成核剂对挤出SPVC发泡体系性能的影响[J]. 塑料, 2005, 34(3): 32-34.
[20]	ZHOU J, LUO X G, LIN X Y. Progress and prospect of the degradable foams of starch and lignin[J]. Chemical Industry and Engineering Progress, 2006, 25(8): 923-928.
[20]	肖锋,叶建东,王迎军. 超声技术在无机材料合成与制备中的应用[J]. 硅酸盐学报, 2002, 30(5): 615-619.
[21]	XUE Z H, ZHAO G J. Crystal properties of montmorilonite-wood composite[J]. Journal of Beijing Forestry University, 2008, 30(1): 114-118.
[21]	周建, 罗学刚, 林晓艳. 淀粉和木质素可降解发泡材料研究进展及展望[J]. 化工进展, 2006, 25(8): 923-928.
[22]	General Administration of Quality Supervision, Inspection and Quarantine of the Peoples Republic of China. Classification on burning behavior for building materials: GB8624—1997[S]. Beijing: Standards Press of China, 1997.
[22]	薛振华, 赵广杰. 蒙脱土/木材复合材料的结晶性能[J]. 北京林业大学学报, 2008, 30(1): 114-118.
[23]	WANG D,ZHU J,YAO Q,et al. A comparison of various methods for the preparation of polystyrene and poly(methyl methacrylate) clay nanocomposites[J]. Chem Mater, 2002, 14(9): 3837-3843.
[24]	XU Z B, TANG X L, ZHENG J Y. Thermal stability and flame retardancy of rigid polyurethane foams/organoclay nanocomposites[J].Polymer-Plastics Technology and Engineering, 2008, 47(10):1136-1141.
[25]	国家技术监督局. 建筑材料燃烧性能分级方法:GB8624—1997[S]. 北京:中国标准出版社,1997.
[26]	TAKASHI K, SHIELDS J R, RICHARD H, et al. Flame-retardant mechanism of silica: effects of resin molecular weight[J]. Journal of Applied Polymer Science, 2003, 87(9):1541-1553.
[27]	TAKASHI K, SHIELDS J R, RICHARD H, et al. Flame retardant mechanism of polyamide 6-clay nanocomposites[J]. Polymer, 2004, 45(3): 881-891.

[1]	Shen Xihuan, Li Huafeng, Zhao Shejiao, Ma Jianwei, Li Shujing, Wang Jun. Investigation and analysis of seedling and experiment plantation of 40 half-sib-families from 4 seed provenances of Pinus tabuliformis[J]. Journal of Beijing Forestry University, 2022, 44(4): 47-53. DOI: 10.12171/j.1000-1522.20210243
[2]	Zhou Hongxin, Didar Xerdiman, Li Shaocai, Sun Hailong, Tan Changming, Wang Xiaowen, Xia Min. Experiment on shrub spray sowing technology in limestone dreg field[J]. Journal of Beijing Forestry University, 2022, 44(1): 87-93. DOI: 10.12171/j.1000-1522.20210187
[3]	Meng Zhaoxin, Cao Jiajia, Zhu Li, Ma Jingyao, Shi Jinsong. Kinetics analysis and strategy of compensation control study for feeding platform of curve saw for wood[J]. Journal of Beijing Forestry University, 2020, 42(2): 159-166. DOI: 10.12171/j.1000-1522.20190234
[4]	Wang Yuanming, Zhang Fangyu, Yang Xuechun, Wang Lihai, Dong Zengchuan. Wave elimination mechanism of wavebreak forest by physical experiments in Baidajie Dike, Nenjiang River of northeastern China[J]. Journal of Beijing Forestry University, 2019, 41(10): 121-127. DOI: 10.13332/j.1000-1522.20180035
[5]	Li Xiang, Wang Yaming, Meng Chen, Li Jiao, Niu Jianzhi. A dynamic crown interception model based on simulated rainfall experiments of small trees[J]. Journal of Beijing Forestry University, 2018, 40(4): 43-50. DOI: 10.13332/j.1000-1522.20170348
[6]	WANG Chao, WANG Dong-mei, LI Yong-hong, ZHANG Yan, LAI Wen-hao. Introduction experiment of bio-energy plant Xanthoceras sorbifolia in the gully region of the loess tableland residue in Shanxi Province,northern China.[J]. Journal of Beijing Forestry University, 2013, 35(3): 90-96.
[7]	LI Yan-jie, XU Chen, LU Yuan-jia, ZHAO Dong. Finite element analysis and experiments on the drill of earth auger[J]. Journal of Beijing Forestry University, 2013, 35(2): 112-117.
[8]	ZHANG Jun-mei, LI Wen-bin, SA Chao, WANG De-ming. Motion control system of remote control pruning robot for standing trees[J]. Journal of Beijing Forestry University, 2007, 29(4): 33-36. DOI: 10.13332/j.1000-1522.2007.04.008
[9]	ZHANG Jun-mei, LI Wen-bin, SA Chao, WANG De-ming. Power control system of remote control pruning robot for standing trees[J]. Journal of Beijing Forestry University, 2007, 29(4): 22-26. DOI: 10.13332/j.1000-1522.2007.04.006
[10]	WANG An-zhi, LIU Jian-mei, PEI Tie-fan, JIN Chang-jie. An experiment and model construction of rainfall interception by Picea koraiensis[J]. Journal of Beijing Forestry University, 2005, 27(2): 38-42.

Cited By

Cited by

Periodical cited type(11)

1.	杨涛，孙付春，黄波，吴柏强，冉光泽. 果园作业平台关键技术研究进展. 中国农机化学报. 2024(01): 152-159 .
2.	汪若尘，蒋亦勇，丁仁凯，孙泽宇，徐可. 基于BP神经网络PID的机电式作业机全向调平控制. 农业工程学报. 2024(23): 52-62 .
3.	姜欢龙，严重勇，李青涛，梁丽，李佳阳，谭芸颖. 自走式农业机械静态稳定性研究现状及展望. 西华大学学报(自然科学版). 2023(01): 32-41 .
4.	聂昭成，罗红品，刘威，李光林. 丘陵山地作物信息采集全向自平衡装置的设计与试验. 西南大学学报(自然科学版). 2023(10): 129-138 .
5.	蒋俞，孙泽宇，汪若尘，夏长高，叶青，郭逸凡. 丘陵山区履带式作业机全向调平系统设计与性能试验. 农业工程学报. 2023(18): 64-73 .
6.	孙泽宇，夏长高，蒋俞，郭逸凡，汪若尘. 基于QBP-PID的履带式作业机全向调平控制研究. 农业机械学报. 2023(12): 397-406 .
7.	姜彪，付友，郭靖，张海林，马新华. 煤矿抢险移动式自动调平搭载平台控制系统. 煤矿机械. 2022(04): 181-185 .
8.	张翠英，仪垂良，刘学峰，任冬梅，张成保. 基于CAN总线的悬浮式转向驱动桥电气控制系统设计. 农业装备与车辆工程. 2021(05): 1-5 .
9.	缪友谊，陈小兵，朱继平，袁栋，陈伟，丁艳. 果园作业平台研究进展分析. 中国农机化学报. 2021(06): 41-49 .
10.	李林林，邓干然，林卫国，崔振德，何冯光，李国杰. 农业机械自动调平技术发展现状与趋势. 现代农业装备. 2021(05): 2-7+35 .
11.	吕昊暾，胡召田，于泳超，康峰，郑永军. 果园高位作业平台自动调平前馈PID控制方法. 农业工程学报. 2021(18): 20-28 .

Other cited types(5)

Get Citation

PDF

XML

Article views (2020) PDF downloads (21) Cited by(16)

Turn off MathJax

Article Contents

Abstract

References

Preparation and structure characterization of biomass polyurethane rigid foam.

Abstract

References

Related Articles

Cited by

Periodical cited type(11)

Other cited types(5)

Catalog

Preparation and structure characterization of biomass polyurethane rigid foam.

Abstract

References

Related Articles

Cited by

Periodical cited type(11)

Other cited types(5)

Catalog

Export File

Citation

Format

Content