Preparation and structure characterization of biomass polyurethane rigid foam.

ZHOU Yu; HAN Wang; ZHAO Li-qing; AN Zhen.

doi:10.13332/j.1000-1522.20160068

Journal of Beijing Forestry University > 2016 > 38(10): 123-129. > DOI: 10.13332/j.1000-1522.20160068

ZHOU Yu, HAN Wang, ZHAO Li-qing, AN Zhen.. Preparation and structure characterization of biomass polyurethane rigid foam.[J]. Journal of Beijing Forestry University, 2016, 38(10): 123-129. DOI: 10.13332/j.1000-1522.20160068

Citation:

PDF (5402 KB)

Preparation and structure characterization of biomass polyurethane rigid foam.

College of Materials Science and Art Design, lnner Mongolia Agricultural University, Hohhot, 010018, P.R.China.

More Information

Received Date: March 03, 2016
Published Date: October 28, 2016

Graphical Abstract

Abstract

Abstract

In order to study the optimal preparation technological procedure for biomass polyurethane rigid foam, we take liquefaction products of Salix cheilophila and isocyanate as main ingredients, OMMT as nucleating agents, stannous octoate as a catalyst, water as foaming agent for foam experiment. The effects of isocyanate, stannous octoate, OMMT and water on the apparent density and compression strength of foam were studied. The structure performance of the foam was characterized and tested by XRD, TEM, SEM and TG analysis respectively. The results showed that the influence of factors on foams followed the sequence of catalyst, foaming agent, stannous octoate and foaming agent. Under optimal conditions, the foaming material had about 0.094 g/cm3 density and 0.416 MPa compression strength. Intercalated or exfoliated OMMT can be prepared by adding just the right amount, which can significantly improve the mechanical properties, thermal stability and flame retardance of materials.
- Salix cheilophila,
- liquefaction product,
- polyurethane foam,
- foaming process

FullText(HTML)

References (49)

References

[1]	谢涛, 谌凡更. 木材液化及其在高分子材料中的应用[J]. 纤维素科学与技术, 2004, 12(2): 47-53.
[1]	XIE T, SHEN F G. Wood liquefaction and application in polymer materials[J]. Journal of Cellulose Science and Technology, 2004, 12(2): 47-53.
[2]	LUO B, QIN T F, LI G Y. Liquefaction of wood and its utilizations[J]. China Wood Industry, 2004, 18(5): 5-7.
[2]	罗蓓, 秦特夫, 李改云. 木材的液化及其利用[J]. 木材工业, 2004, 18(5): 5-7.
[3]	周宇, 安珍. 沙柳材液化的工艺研究及产物分析[J]. 东北林业大学学报, 2015, 43(10): 109-113.
[3]	ZHOU Y, AN Z .Study on the liquefaction of salix and products analysis[J]. Journal of Northeast Forestry University, 2015, 43(10): 109-113.
[4]	ZHANG Q H, ZHAO G J. Research progress on mechanism of wood liquefaction reaction in phenol and polyhydric alcohols[J]. Chemistry and Industry of Forest Products,2014,34(4):138-143.
[4]	张求慧, 赵广杰. 木材的苯酚及多元醇液化反应机理研究进展[J]. 林产化学与工业,2014,34(4): 138-143.
[5]	HUANG J T,GAO G H. Aanlysis of NMR spectra on liquefied products from Salix psammophila and Caragana intermedia woods[J]. Chemistry and Industry of Forest Products, 2009, 29(4): 101-104.
[5]	黄金田, 高冠慧. 沙柳及柠条灌木材液化产物的核磁共振谱分析[J]. 林产化学与工业, 2009, 29(4):101-104.
[6]	ZHAO Y. The study on the technology and performance of the liquefaction product of salix[D]. Huhhot: Inner Mongolia Agricultural University, 2013.
[6]	赵岩. 沙柳液化物制备发泡材料的工艺与性能的研究[D]. 呼和浩特:内蒙古农业大学, 2013.
[7]	SHA F, MA D Q, LIU G, et al. Development and characterization of insulation decorative board with rigid polyurethane foam[J]. Building Energy Efficiency, 2010, 38(12):53-57.
[7]	沙丰, 马德强, 刘钢,等. 硬泡聚氨酷保温装饰板的开发与性能表征[J]. 建筑节能, 2010, 38(12): 53-57.
[8]	STOJANOVIAC＇U2 B V, JANEVSKI J N, MITKOVIAC＇U2 P B, et al. Thermally activated building systems in context of increasing building energy efficiency[J]. Thermal Science, 2014, 8(3): 1011-1018.
[8]	CHEN Y L, SHANG S S, YAN M, et al. Research status of thermal insulation wall materials[J]. Advanced Ceramics, 2015 (3): 20-24.
[9]	陈艳林, 尚珊珊, 严明,等. 保温隔热墙体材料的研究现状[J]. 现代技术陶瓷, 2015 (3): 20-24.
[9]	Standardization Administration of the People’s Republic of China. Cellular plastics and rubbers: determination of apparent density: GB/T 6343—2009[S]. Beijing: Standards Press of China, 2009.
[10]	Standardization Administration of the People’s Republic of China. Rigid cellular plastics: determination of compression properties: GB/T 8813—2008[S]. Beijing: Standards Press of China, 2008.
[10]	中国国家标准化管理委员会. 泡沫塑料及橡胶表观密度的测定:GB/T 6343—2009[S]. 北京: 中国标准出版社,2009.
[11]	中国国家标准化管理委员会. 硬质泡沫塑料压缩性能的测定:GB/T 8813—2008[S]. 北京:中国标准出版社,2008.
[11]	Standardization Administration of the People’s Republic of China. Plastics: determination of burning behavior by oxygen index: part 2: ambient-temperature test: GB/T2406.2—2009[S]. Beijing: Standards Press of China, 2009.
[12]	中国国家标准化管理委员会. 塑料:用氧指数法测定燃烧行为第2部分:室温试验:GB/T2406.2—2009[S]. 北京:中国标准出版社,2009.
[12]	LIU L Q, SUN F W, LIU Y, et al. Overview of bamboo liquefaction research and its applications[J]. China Wood Industry, 2012, 26(1): 15-19.
[13]	刘乐群, 孙丰文, 刘杨,等.竹材液化制备墙体新材料的研究进展[J]. 木材工业, 2012, 26(1): 15-19.
[13]	LIU Y H, GAO L L, LUO A X, et al. Polyurethane foams made from combined liquefaction mixtures of bamboo residues and starch[J]. Acta Polymerica Sinica, 2008(6): 544-549.
[14]	MIAO Y W. Preparation and properties of sandwich foam composite materials reinforced by SiC nanoparticles[D]. Huhhot: Inner Mongolia Agricultural University, 2014.
[14]	刘玉环, 高龙兰, 罗爱香,等. 毛竹屑与玉米淀粉共液化产物制备聚氨酯泡沫研究[J]. 高分子学报, 2008(6): 544-549.
[15]	WANG T P, MAO Z H. Effects of catalysts on mechanical properties of polyuerthane foams based on corn stalk[J]. Renewable Energy Resources, 2009, 27(6): 50-53,57.
[15]	苗雅文. SiC纳米粒子强化“三明治”发泡复合材料制备及其性能研究[D]. 呼和浩特:内蒙古农业大学,2014.
[16]	CAO X W, HE D, WU W, et al. Study on the effect of CaCO3 on open-cell foaming performance of polypropylene [J]. China Plastics Industry, 2011, 39(9): 57-60.
[16]	王体朋, 毛志怀. 催化剂对玉米秸秆基聚氨酯泡沫机械性能影响的研究[J]. 可再生能源, 2009, 27(6): 50-53,57.
[17]	HAN J Z, XIA Y, CAI Y F. Research progress of polymer/montmorillonite nanocomposites[J]. Plastics Manufacture, 2006, 34(10): 66-70.
[17]	曹贤武,何丁, 伍巍,等. 成核剂CaCO3对聚丙烯开孔发泡性能影响的研究[J]. 塑料工业, 2011, 39(9): 57-60.
[18]	韩建竹, 夏英, 蔡月芬. 聚合物/蒙脱土纳米复合材料的研究进展[J]. 塑料制造, 2006, 34(10): 66-70.
[18]	WANG G Y, CUI Y, LIN Y, et al. Effect of nucleate agent on mechanical properties of soft poly(vinyl chloride) extrusion foamed material[J]. Plastics, 2005, 34(3): 32-34.
[19]	XIAO F, YE J D, WANG Y J. Application of ultrasonic technique in the processing and synthesis of inorganic materials[J]. Journal of the Chinese Ceramic Society, 2002, 30(5): 615-619.
[19]	王国英, 崔毅, 林园,等. 成核剂对挤出SPVC发泡体系性能的影响[J]. 塑料, 2005, 34(3): 32-34.
[20]	ZHOU J, LUO X G, LIN X Y. Progress and prospect of the degradable foams of starch and lignin[J]. Chemical Industry and Engineering Progress, 2006, 25(8): 923-928.
[20]	肖锋,叶建东,王迎军. 超声技术在无机材料合成与制备中的应用[J]. 硅酸盐学报, 2002, 30(5): 615-619.
[21]	XUE Z H, ZHAO G J. Crystal properties of montmorilonite-wood composite[J]. Journal of Beijing Forestry University, 2008, 30(1): 114-118.
[21]	周建, 罗学刚, 林晓艳. 淀粉和木质素可降解发泡材料研究进展及展望[J]. 化工进展, 2006, 25(8): 923-928.
[22]	General Administration of Quality Supervision, Inspection and Quarantine of the Peoples Republic of China. Classification on burning behavior for building materials: GB8624—1997[S]. Beijing: Standards Press of China, 1997.
[22]	薛振华, 赵广杰. 蒙脱土/木材复合材料的结晶性能[J]. 北京林业大学学报, 2008, 30(1): 114-118.
[23]	WANG D,ZHU J,YAO Q,et al. A comparison of various methods for the preparation of polystyrene and poly(methyl methacrylate) clay nanocomposites[J]. Chem Mater, 2002, 14(9): 3837-3843.
[24]	XU Z B, TANG X L, ZHENG J Y. Thermal stability and flame retardancy of rigid polyurethane foams/organoclay nanocomposites[J].Polymer-Plastics Technology and Engineering, 2008, 47(10):1136-1141.
[25]	国家技术监督局. 建筑材料燃烧性能分级方法:GB8624—1997[S]. 北京:中国标准出版社,1997.
[26]	TAKASHI K, SHIELDS J R, RICHARD H, et al. Flame-retardant mechanism of silica: effects of resin molecular weight[J]. Journal of Applied Polymer Science, 2003, 87(9):1541-1553.
[27]	TAKASHI K, SHIELDS J R, RICHARD H, et al. Flame retardant mechanism of polyamide 6-clay nanocomposites[J]. Polymer, 2004, 45(3): 881-891.

Cited By

Cited by

Periodical cited type(40)

1.	张金博，杨圆圆，徐柏松，曹颖，赫亮，冯健. 红松半同胞家系生长性状变异及优良家系和单株的筛选. 东北林业大学学报. 2024(02): 9-12+20 .
2.	李学波. 遮阴处理对4个种源核桃楸幼苗光合特性的影响. 吉林林业科技. 2024(01): 1-6+12 .
3.	陆斐，刘刚，陈晓波，柏景珊，郭郁娇，魏伟，王刚. 露水河沙松优良家系与优良单株初选. 北华大学学报(自然科学版). 2024(05): 589-596 .
4.	尚福强，高源，马晓雨，李连强，张利民，张丽艳，张杰，冯健. 红松优树半同胞家系的遗传变异及优良家系和单株选择. 东北林业大学学报. 2024(10): 1-6 .
5.	王佳兴，闫平玉，孙佰飞，刘劲宏，冯可乐，张含国. 长白落叶松自由授粉家系生长变异及优良家系早期选择. 南京林业大学学报(自然科学版). 2024(05): 81-89 .
6.	熊欢欢，张海啸，李艳霞. 果用红松优良无性系选择研究. 林业科技. 2024(06): 38-42+71 .
7.	赵林峰，高建亮，彭劲松，姜小文. 3种类型杉木林分生长、密度和材质的综合评价. 安徽农业大学学报. 2023(01): 29-35 .
8.	于海洋，辛菁锴，王晓梅，宋巍巍，张艳明，张林，杨雨春，毕成程. 红松亲本无性系生长性状变异选择研究. 防护林科技. 2023(04): 63-67 .
9.	于海洋，庞忠义，殷春红，丁昌俊，王福森，张金旺，金培林，付志祥，曲冠证，赵曦阳. 100个杨树无性系生长及材性变异研究. 西北林学院学报. 2023(04): 134-142+155 .
10.	郑如德，钱国财，潘昕，汤行昊，范辉华. 木荷优树自由授粉家系生长性状分析与早期选择. 防护林科技. 2023(05): 17-22 .
11.	周炳秀，刘勇，彭玉信，张劲，赵建松，朱轶超，赵巧玲，王硕，陶靖，孟路. 雄性毛白杨无性系苗期表型和生理变异的早期综合评价. 东北林业大学学报. 2023(11): 1-9 .
12.	尹一卜，李吉祥，郭樱杰，芦子廷，肖英，刘华领，詹亚光，曾凡锁. 白蜡属种间杂交子代木质素含量变异及FmPAL核苷酸多态性关联分析. 植物研究. 2022(02): 191-199 .
13.	魏嘉彤，陈思琪，芦贤博，张非凡，潘振海，柳妍如，葛丽丽，赵曦阳. 基于生长与木材性状的红松优良种源评价选择. 北京林业大学学报. 2022(03): 12-23 . 本站查看
14.	赵林峰，高建亮. 杉木速生无性系生长与形质性状的遗传变异与良种选择. 中南林业科技大学学报. 2022(03): 8-15 .
15.	贾庆彬，刘庚，赵佳丽，李奎友，孙文生. 红松半同胞家系生长性状变异分析与优良家系选择. 南京林业大学学报(自然科学版). 2022(04): 109-116 .
16.	罗芊芊，肖德卿，徐洪辉，王建华，刘志明，陈雅，万文娟，邓章文. 马尾松无性系生长和形质性状变异分析和优选. 东北林业大学学报. 2022(09): 40-44 .
17.	欧阳天林，朱柯帆，邱建勋，刘武阳，邱全生，肖德卿，王云鹏，周志春. 木荷种子园自由授粉家系生长遗传变异及初选. 中南林业科技大学学报. 2022(09): 17-23 .
18.	王芳，陆志民，王君，张世凯，李峪曦，李绍臣，张建秋，杨雨春. 低温胁迫下红松与西伯利亚红松光合与气孔特性. 植物研究. 2021(02): 205-212 .
19.	刘晓婷，魏嘉彤，吴培莉，吴琳，徐清山，房衍林，杨斌，赵曦阳. 吉林省天然红松居群表型变异分析及多样性研究. 北京林业大学学报. 2021(04): 25-34 . 本站查看
20.	李岩，朱嘉瑶，王喜和，孙权，李玉磊，吴蕴洋，李德尧，李平扬，于海洋，赵曦阳. 红松优树无性系及其子代的生长评价与选择研究. 北京林业大学学报. 2021(10): 38-46 . 本站查看
21.	乔滨杰，王德秋，高海燕，李召珉，葛丽丽，丁文雅，赵曦阳. 干旱胁迫下杨树无性系苗期光合与气孔形态变异研究. 植物研究. 2020(02): 177-188 .
22.	李嘉琪，韩喜东，马盈慧，李月季，王立祥，韩喜田，刘志，李海民，赵曦阳. 樟子松无性系生长性状与结实量变异研究. 植物研究. 2020(02): 217-223 .
23.	王芳，陆志民，王元兴，杨雨春. 233个红松优树半同胞家系的生长性状变异研究. 吉林林业科技. 2020(02): 1-4+24 .
24.	刘晓婷，李嘉琪，李峪曦，赵男，胡佰策，高海燕，李召珉，葛丽丽，丁文雅，赵曦阳. 红松半同胞家系变异分析及优良家系选择. 分子植物育种. 2020(13): 4473-4482 .
25.	蒋路平，王景源，张鹏，梁德洋，张秦徽，王碧莹，裴晓娜，赵曦阳. 170个红松无性系生长及结实性状变异及选择. 林业科学研究. 2019(01): 58-64 .
26.	郭文丽，李义良，赵奋成，铁军，廖仿炎，钟岁英，林昌明，叶威方. 湿加松无性系表型遗传多样性研究. 植物研究. 2019(02): 259-266 .
27.	王璧莹，赵曦阳，王洪武，姜国云，沈光，王连奎，李焱龙，林健，王忠良. 依据生长性状对红松半同胞家系的评价选择. 东北林业大学学报. 2019(04): 8-11+20 .
28.	潘艳艳，许贵友，董利虎，王成录，梁德洋，赵曦阳. 日本落叶松全同胞家系苗期生长性状遗传变异. 南京林业大学学报(自然科学版). 2019(02): 14-22 .
29.	王芳，王元兴，王成录，张伟娜，刘卫胜，陆志民，杨雨春. 红松优树半同胞子代家系生长、结实及抗病虫能力的变异特征. 应用生态学报. 2019(05): 1679-1686 .
30.	张秦徽，王洪武，姜国云，沈光，王连奎，李焱龙，王雷，王立祥，李月季，李蕊，赵曦阳. 红松半同胞家系变异分析及选择研究. 植物研究. 2019(04): 557-567 .
31.	刘雨林，张兰，王元兴，任炳忠，王寅亮. 长白山红松林针叶次生代谢产物研究. 安徽农学通报. 2019(20): 28-31 .
32.	张秦徽，李蕊，王璧莹，Kombi Kaviriri David，裴晓娜，王忠良，梁德洋，张鹏，赵曦阳. 红松开花结实研究进展. 分子植物育种. 2019(04): 1364-1372 .
33.	李光森. 红松多无性系群体的种实性状变异研究. 农业开发与装备. 2018(06): 110 .
34.	姜国云，蒋路平，宋双林，王井源，王淇，王连福，张鹏，赵曦阳. 红松半同胞家系遗传变异分析及果材兼用优良家系选择. 植物研究. 2018(05): 775-784 .
35.	潘艳艳，梁德洋，郭婧，王芳，王福维，李树春，赵曦阳. 日本落叶松不同种源及家系生长性状变异分析. 北京林业大学学报. 2018(11): 19-27 . 本站查看
36.	隋立龙，王芳，赵泉湖，王太坤，姜鑫，王君，陆志民，杨雨春. 不同林分红松生长与结实性状比较研究. 植物研究. 2018(06): 886-893 .
37.	刘德栋. 我国红松良种选育研究进展. 防护林科技. 2017(03): 96-99+116 .
38.	廖怀建，邓疆，杜婷，石雷，周成理. 引进种源印度黄檀优株选择及优良无性系选择与评价. 林业科学研究. 2017(06): 916-920 .
39.	Shaopeng Yin，Zhenhai Xiao，Guohui Zhao，Xin Zhao，Xiaoyang Sun，Ying Zhang，Fuwei Wang，Shuchun Li，Xiyang Zhao，Guan-Zheng Qu. Variation analyses of growth and wood properties of Larix olgensis clones in China. Journal of Forestry Research. 2017(04): 687-697 .
40.	张鑫鑫，夏辉，赵昕，张莹，李光岩，张磊，孙晓阳，韩冬荟，赵曦阳. 长白落叶松种子园亲本生长与结实性状综合评价. 植物研究. 2017(06): 933-940 .

Other cited types(22)

Get Citation

PDF

XML

Article views (2020) PDF downloads (21) Cited by(62)

Turn off MathJax

Article Contents

Abstract

References

Preparation and structure characterization of biomass polyurethane rigid foam.

Abstract

References

Cited by

Periodical cited type(40)

Other cited types(22)

Catalog

Export File

Citation

Format

Content